Nitrosyl isomerism in amorphous Mn(TPP)(NO) solids

Reaction of NO with amorphous Mn(TPP) layers gives two Mn(TPP)(NO) isomers with linear and bent Mn-N-O geometries that reversibly interconvert with changes in temperature. DFT computations predict that the linear complex is the singlet ground state while the bent structure is a triplet state.

Uloženo v:
Podrobná bibliografie
Vydáno v:Chemical communications (Cambridge, England) Ročník 48; číslo 99; s. 12088
Hlavní autoři: Kurtikyan, Tigran S, Hayrapetyan, Vardan A, Martirosyan, Garik G, Ghazaryan, Robert K, Iretskii, Alexei V, Zhao, Hailiang, Pierloot, Kristine, Ford, Peter C
Médium: Journal Article
Jazyk:angličtina
Vydáno: England 25.12.2012
Témata:
Coordination Complexes - chemistry
Isomerism
Manganese - chemistry
Nitric Oxide - chemistry
Spectroscopy, Fourier Transform Infrared
Temperature
ISSN:1364-548X, 1364-548X
On-line přístup:Zjistit podrobnosti o přístupu
Tagy: Přidat tag
Žádné tagy, Buďte první, kdo vytvoří štítek k tomuto záznamu!
Popis
Shrnutí:Reaction of NO with amorphous Mn(TPP) layers gives two Mn(TPP)(NO) isomers with linear and bent Mn-N-O geometries that reversibly interconvert with changes in temperature. DFT computations predict that the linear complex is the singlet ground state while the bent structure is a triplet state.
Bibliografie:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1364-548X
1364-548X
DOI:10.1039/c2cc37337h