A new direct MP2 gradient algorithm with implementation on a massively parallel computer

A new direct second-order Møller-Plesset gradient algorithm is presented. By avoiding generation of molecular orbital integrals with three virtual indices, the memory requirement for a calculation with n basis functions and o occupied orbitals is reduced to on 2, and overall computational savings ar...

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Veröffentlicht in:Chemical physics letters Jg. 255; H. 1; S. 210 - 216
1. Verfasser: Nielsen, Ida M.B.
Format: Journal Article
Sprache:Englisch
Veröffentlicht: Elsevier B.V 07.06.1996
ISSN:0009-2614, 1873-4448
Online-Zugang:Volltext
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Zusammenfassung:A new direct second-order Møller-Plesset gradient algorithm is presented. By avoiding generation of molecular orbital integrals with three virtual indices, the memory requirement for a calculation with n basis functions and o occupied orbitals is reduced to on 2, and overall computational savings are obtained. The algorithm has been implemented with distributed data on a massively parallel computer, the Intel Paragon. The parallelization scheme provides high parallel efficiency, and the performance of the algorithm is illustrated for calculations running on up to 64 processors.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(96)00356-9