Synthesis of large crystals of all-silica zeolite ferrierite

In this paper, the non-aqueous organothermal synthesis of large crystals of zeolite ferrierite is described. The influence of unbranched monoalkyl C 3–C 5 amines, different gel compositions and crystallization conditions is studied. These parameters have a significant impact on crystal form. The lar...

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Bibliographic Details
Published in:Microporous and mesoporous materials Vol. 104; no. 1; pp. 179 - 184
Main Authors: Rakoczy, Rainer A., Traa, Yvonne, Kortunov, Pavel, Vasenkov, Sergey, Kärger, Jörg, Weitkamp, Jens
Format: Journal Article
Language:English
Published: Amsterdam Elsevier Inc 23.08.2007
Elsevier
Subjects:
Chemistry
Colloidal state and disperse state
Exact sciences and technology
General and physical chemistry
Interference microscopy
Ion-exchange
Large crystals
Mono-alkyl amines
Non-aqueous synthesis
Porous materials
Pyridine
Surface physical chemistry
Zeolite ferrierite
Zeolites: preparations and properties
Non-aqueous synthesis
Mono-alkyl amines
Interference microscopy
Zeolite ferrierite
Pyridine
Large crystals
Nitrogen heterocycle
Crystals
Alkylamine
Zeolite
Silica
Molecular sieve
Amine
Synthesis
Alkyl
Six membered ring
ISSN:1387-1811, 1873-3093
Online Access:Get full text
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Summary:In this paper, the non-aqueous organothermal synthesis of large crystals of zeolite ferrierite is described. The influence of unbranched monoalkyl C 3–C 5 amines, different gel compositions and crystallization conditions is studied. These parameters have a significant impact on crystal form. The large crystals obtained show adsorption properties similar to conventionally synthesized zeolite ferrierite and allowed the observation of the evolution of intracrystalline concentration profiles by interference microscopy.
ISSN:1387-1811
1873-3093
DOI:10.1016/j.micromeso.2007.01.046