Multiple mode exciton-vibrational coupling in H-aggregates: synergistic enhancement of the quantum yield

The impact of exciton-vibrational coupling involving fast and slow vibrational modes on absorption and emission in molecular H-aggregates is investigated using a multimode Holstein Hamiltonian. For H-aggregates composed of rigid molecules the radiative decay rate is rigorously zero due to the asymme...

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Bibliographic Details
Published in:The Journal of chemical physics Vol. 132; no. 9; p. 094704
Main Authors: Spano, F C, Silvestri, Leonardo
Format: Journal Article
Language:English
Published: United States 07.03.2010
ISSN:1089-7690, 1089-7690
Online Access:Get more information
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