Ionic liquids in dispersive liquid-liquid microextraction
•Ionic liquids (ILs) applied in dispersive liquid-liquid microextraction (DLLME).•Dispersive solvents (organics, surfactants or hydrophilic ILs) not always needed.•Summary of determinations of metals and organic compounds in various samples.•IL-based surfactants can be used for solids analysis and i...
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| Veröffentlicht in: | TrAC, Trends in analytical chemistry (Regular ed.) Jg. 51; S. 87 - 106 |
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| Hauptverfasser: | , , , |
| Format: | Journal Article |
| Sprache: | Englisch |
| Veröffentlicht: |
Elsevier B.V
01.11.2013
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| ISSN: | 0165-9936, 1879-3142 |
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| Abstract | •Ionic liquids (ILs) applied in dispersive liquid-liquid microextraction (DLLME).•Dispersive solvents (organics, surfactants or hydrophilic ILs) not always needed.•Summary of determinations of metals and organic compounds in various samples.•IL-based surfactants can be used for solids analysis and in-situ IL-DLLME.
In this review, we summarize the most recent analytical developments aimed at employing Ionic liquids (ILs) in dispersive liquid-liquid microextraction (DLLME). Four main operation modes can be distinguished: (1) conventional IL-DLLME; (2) temperature-controlled IL-DLLME; (3a) ultrasound-assisted, (3b) microwave-assisted or (3c) vortex-assisted IL-DLLME; and, (4) in-situ IL-DLLME. In these modes, the dispersive solvent can be an organic solvent, a surfactant, or a hydrophilic IL. In some cases, a dispersive solvent is not even necessary. We discuss practical applications of IL-DLLME to determine metals and organic compounds in a variety of samples. |
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| AbstractList | •Ionic liquids (ILs) applied in dispersive liquid-liquid microextraction (DLLME).•Dispersive solvents (organics, surfactants or hydrophilic ILs) not always needed.•Summary of determinations of metals and organic compounds in various samples.•IL-based surfactants can be used for solids analysis and in-situ IL-DLLME.
In this review, we summarize the most recent analytical developments aimed at employing Ionic liquids (ILs) in dispersive liquid-liquid microextraction (DLLME). Four main operation modes can be distinguished: (1) conventional IL-DLLME; (2) temperature-controlled IL-DLLME; (3a) ultrasound-assisted, (3b) microwave-assisted or (3c) vortex-assisted IL-DLLME; and, (4) in-situ IL-DLLME. In these modes, the dispersive solvent can be an organic solvent, a surfactant, or a hydrophilic IL. In some cases, a dispersive solvent is not even necessary. We discuss practical applications of IL-DLLME to determine metals and organic compounds in a variety of samples. In this review, we summarize the most recent analytical developments aimed at employing Ionic liquids (ILs) in dispersive liquid-liquid microextraction (DLLME). Four main operation modes can be distinguished: (1) conventional IL-DLLME; (2) temperature-controlled IL-DLLME; (3a) ultrasound-assisted, (3b) microwave-assisted or (3c) vortex-assisted IL-DLLME; and, (4) in-situ IL-DLLME. In these modes, the dispersive solvent can be an organic solvent, a surfactant, or a hydrophilic IL. In some cases, a dispersive solvent is not even necessary. We discuss practical applications of IL-DLLME to determine metals and organic compounds in a variety of samples. |
| Author | Pino, Verónica Trujillo-Rodríguez, María J. Afonso, Ana M. Rocío-Bautista, Priscilla |
| Author_xml | – sequence: 1 givenname: María J. surname: Trujillo-Rodríguez fullname: Trujillo-Rodríguez, María J. – sequence: 2 givenname: Priscilla surname: Rocío-Bautista fullname: Rocío-Bautista, Priscilla – sequence: 3 givenname: Verónica surname: Pino fullname: Pino, Verónica email: veropino@ull.edu.es, veropino@ull.es – sequence: 4 givenname: Ana M. surname: Afonso fullname: Afonso, Ana M. |
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| Snippet | •Ionic liquids (ILs) applied in dispersive liquid-liquid microextraction (DLLME).•Dispersive solvents (organics, surfactants or hydrophilic ILs) not always... In this review, we summarize the most recent analytical developments aimed at employing Ionic liquids (ILs) in dispersive liquid-liquid microextraction... |
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| SubjectTerms | Dispersive liquid-liquid microextraction hydrophilicity Ionic liquid ionic liquids liquid-phase microextraction Metal metals microwave treatment Microwave-assisted Organic compound organic compounds Organic solvent Preconcentration Surfactant surfactants Ultrasound-assisted Vortex-assisted |
| Title | Ionic liquids in dispersive liquid-liquid microextraction |
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