Synthesis of pure nano Cr2O3 from chromite ore by a novel method and investigation of its composites with bentonite for their photocatalytic properties

In the present study, nano Cr 2 O 3 was prepared with a novel method from chromite ore. In this method, K 2 Cr 2 O 7 was prepared by alkaline melting of chromite ore. Then, the precursor complex K 3 [Cr(C 2 O 4 ) 3 ] was prepared using potassium dichromate obtained from chromite ore and Merck Co. fo...

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Vydáno v:Journal of the Iranian Chemical Society Ročník 20; číslo 11; s. 2805 - 2819
Hlavní autoři: Khatamian, Maasoumeh, Dastar, Elham, Fazli-Shokouhi, Sara, Hosseini Nami, Shamin
Médium: Journal Article
Jazyk:angličtina
Vydáno: Berlin/Heidelberg Springer Berlin Heidelberg 01.11.2023
Springer Nature B.V
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ISSN:1735-207X, 1735-2428
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Abstract In the present study, nano Cr 2 O 3 was prepared with a novel method from chromite ore. In this method, K 2 Cr 2 O 7 was prepared by alkaline melting of chromite ore. Then, the precursor complex K 3 [Cr(C 2 O 4 ) 3 ] was prepared using potassium dichromate obtained from chromite ore and Merck Co. for comparing their purity. Therefore, two types of nano (Cr 2 O 3 ) M or ch (M = Merck, ch = chromite ore) were prepared by destructing the gel contained K 3 [Cr(C 2 O 4 ) 3 ] and starch as an eco-friendly material for controlling the size and morphology of the nanoparticles. So, these nanoparticles were characterized by XRD, FESEM, and EDX. The ball-milled bentonite (B) was used for the preparation of (Cr 2 O 3 (n% = 30, 50, and 70%)/B) ch and (Cr 2 O 3 (n% = 30, 50%)/B) M nanocomposites. The XRD and FESEM of (Cr 2 O 3 (n%)/B) ch and (Cr 2 O 3 (n%)/B) M are the same. So, the (Cr 2 O 3 (n%)/B) ch nanocomposites were just used for further investigations, such as photocatalytic properties, and analysed by other techniques, including FTIR and DRS. The (Cr 2 O 3 (30%)/B) ch showed the highest degradation property, 69% after 240 min, among other prepared nanocomposites to destroy methylene blue with 10 ppm concentration at pH = 10 under UV irradiation. Also, the (Cr 2 O 3 (30%)/B) ch could degrade methyl orange with 10 ppm concentration at pH = 7 up to 74% after 240 min. Nano Cr 2 O 3 and bare bentonite efficiency for methylene blue and methyl orange degradation were lower (< 30%) under the same conditions.
AbstractList In the present study, nano Cr 2 O 3 was prepared with a novel method from chromite ore. In this method, K 2 Cr 2 O 7 was prepared by alkaline melting of chromite ore. Then, the precursor complex K 3 [Cr(C 2 O 4 ) 3 ] was prepared using potassium dichromate obtained from chromite ore and Merck Co. for comparing their purity. Therefore, two types of nano (Cr 2 O 3 ) M or ch (M = Merck, ch = chromite ore) were prepared by destructing the gel contained K 3 [Cr(C 2 O 4 ) 3 ] and starch as an eco-friendly material for controlling the size and morphology of the nanoparticles. So, these nanoparticles were characterized by XRD, FESEM, and EDX. The ball-milled bentonite (B) was used for the preparation of (Cr 2 O 3 (n% = 30, 50, and 70%)/B) ch and (Cr 2 O 3 (n% = 30, 50%)/B) M nanocomposites. The XRD and FESEM of (Cr 2 O 3 (n%)/B) ch and (Cr 2 O 3 (n%)/B) M are the same. So, the (Cr 2 O 3 (n%)/B) ch nanocomposites were just used for further investigations, such as photocatalytic properties, and analysed by other techniques, including FTIR and DRS. The (Cr 2 O 3 (30%)/B) ch showed the highest degradation property, 69% after 240 min, among other prepared nanocomposites to destroy methylene blue with 10 ppm concentration at pH = 10 under UV irradiation. Also, the (Cr 2 O 3 (30%)/B) ch could degrade methyl orange with 10 ppm concentration at pH = 7 up to 74% after 240 min. Nano Cr 2 O 3 and bare bentonite efficiency for methylene blue and methyl orange degradation were lower (< 30%) under the same conditions.
In the present study, nano Cr2O3 was prepared with a novel method from chromite ore. In this method, K2Cr2O7 was prepared by alkaline melting of chromite ore. Then, the precursor complex K3[Cr(C2O4)3] was prepared using potassium dichromate obtained from chromite ore and Merck Co. for comparing their purity. Therefore, two types of nano (Cr2O3)M or ch (M = Merck, ch = chromite ore) were prepared by destructing the gel contained K3[Cr(C2O4)3] and starch as an eco-friendly material for controlling the size and morphology of the nanoparticles. So, these nanoparticles were characterized by XRD, FESEM, and EDX. The ball-milled bentonite (B) was used for the preparation of (Cr2O3(n% = 30, 50, and 70%)/B)ch and (Cr2O3(n% = 30, 50%)/B)M nanocomposites. The XRD and FESEM of (Cr2O3(n%)/B)ch and (Cr2O3(n%)/B)M are the same. So, the (Cr2O3(n%)/B)ch nanocomposites were just used for further investigations, such as photocatalytic properties, and analysed by other techniques, including FTIR and DRS. The (Cr2O3(30%)/B)ch showed the highest degradation property, 69% after 240 min, among other prepared nanocomposites to destroy methylene blue with 10 ppm concentration at pH = 10 under UV irradiation. Also, the (Cr2O3(30%)/B)ch could degrade methyl orange with 10 ppm concentration at pH = 7 up to 74% after 240 min. Nano Cr2O3 and bare bentonite efficiency for methylene blue and methyl orange degradation were lower (< 30%) under the same conditions.
Author Fazli-Shokouhi, Sara
Khatamian, Maasoumeh
Dastar, Elham
Hosseini Nami, Shamin
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  organization: Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz
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  fullname: Fazli-Shokouhi, Sara
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  givenname: Shamin
  surname: Hosseini Nami
  fullname: Hosseini Nami, Shamin
  organization: Faculty of Chemical and Petroleum Engineering, University of Tabriz
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Keywords Bentonite
Chromium oxide/bentonite nanocomposite
Photocatalyst
Nano chromium oxide
Chromite ore
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Snippet In the present study, nano Cr 2 O 3 was prepared with a novel method from chromite ore. In this method, K 2 Cr 2 O 7 was prepared by alkaline melting of...
In the present study, nano Cr2O3 was prepared with a novel method from chromite ore. In this method, K2Cr2O7 was prepared by alkaline melting of chromite ore....
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SubjectTerms Analytical Chemistry
Bentonite
Biochemistry
Chemistry
Chemistry and Materials Science
Chromite
Chromium oxides
Degradation
Dyes
Electron microscopes
Fourier transforms
Inorganic Chemistry
Investigations
Methods
Methylene blue
Nanocomposites
Nanoparticles
Organic Chemistry
Original Paper
Particle size
Photocatalysis
Physical Chemistry
Pollutants
Potassium
Potassium dichromate
Scanning electron microscopy
Semiconductors
Ultraviolet radiation
Water
Water pollution
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Title Synthesis of pure nano Cr2O3 from chromite ore by a novel method and investigation of its composites with bentonite for their photocatalytic properties
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