Electrochemical Dehydrogenative Cross‐Coupling of Quinoxalin‐2(1H)‐ones with Amines for the Synthesis of 3‐Aminoquinoxalinones

An efficient protocol for the synthesis of 3‐aminoquinoxalinones via the electrochemical dehydrogenative C‐3 amination of quinoxalin‐2(1H)‐ones was developed. With aliphatic amines and azoles as the nitrogen sources, a series of 3‐aminoquinoxalinones was obtained in up to 99% yield. This direct elec...

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Veröffentlicht in:	Advanced synthesis & catalysis Jg. 361; H. 5; S. 1033 - 1041
Hauptverfasser:	Li, Ke‐Jing, Xu, Kun, Liu, Yong‐Guo, Zeng, Cheng‐Chu, Sun, Bao‐Guo
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	WEINHEIM Wiley 05.03.2019 Wiley Subscription Services, Inc
Schlagworte:	Aliphatic amines Amines Chemistry Chemistry, Applied Chemistry, Organic Dehydrogenation dehydrogenative cross coupling direct electrolysis Heterocyclic compounds oxidative amination Oxidizing agents Physical Sciences quinoxalinone Science & Technology Synthesis Transition metals FUNCTIONALIZATION DESIGN POTENT oxidative amination BIOLOGICAL-ACTIVITY RECEPTOR quinoxalinone dehydrogenative cross coupling DERIVATIVES direct electrolysis QUINOXALINE
ISSN:	1615-4150, 1615-4169
Online-Zugang:	Volltext
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