Programming Conducting Metal‐Organic Frameworks for Catalysis and Energy

The dynamics of energy and charge storage/conversion in Metal‐Organic Frameworks (MOFs) are closely linked to their photo‐electro‐catalytic properties, which influence their response toward light, electrons, or ions. Herein, MOFs designed or programmed with geometries and intentionally introduced fu...

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Bibliographic Details
Published in:ChemCatChem Vol. 17; no. 10
Main Author: Cirujano, Francisco G.
Format: Journal Article
Language:English
Published: Weinheim Wiley Subscription Services, Inc 01.05.2025
Subjects:
Catalysis
Charge transfer
Charge transport
Energy Storage
Metal-organic frameworks
MOFs
Optoelectronics
Photoexcitation
Photo‐Electro‐catalysis
ISSN:1867-3880, 1867-3899
Online Access:Get full text
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Summary:The dynamics of energy and charge storage/conversion in Metal‐Organic Frameworks (MOFs) are closely linked to their photo‐electro‐catalytic properties, which influence their response toward light, electrons, or ions. Herein, MOFs designed or programmed with geometries and intentionally introduced functionalities are presented, highlighting the advances in defect engineering for increasing reactivity/conductivity and new strategies for enhancing charge transfer dynamics. Several examples of excitation chemistry are reviewed here, including photoexcitation and electrochemical excitation's ability to improve energy/charge transfer, sustainable catalysis, and energy‐related applications of chemical transformations. This review highlights advances in MOF design, including geometry optimization, defect engineering to enhance reactivity and conductivity, and strategies to improve charge transfer dynamics. It also covers excitation chemistry, such as photo‐ and electrochemical excitation, to boost energy/charge transfer and facilitate sustainable catalysis and energy‐related chemical transformations.
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ISSN:1867-3880
1867-3899
DOI:10.1002/cctc.202402154