Tetrazine Chelate Ligands Bridging Two [Ru(acac)2] Fragments: Mixed Valency and Radical Complex Formation

Using bis(3‐methyl‐2‐pyridyl)‐1,2,4,5‐tetrazine 1, 3‐(2‐pyrimidyl)‐6‐methyl‐1,2,4,5‐tetrazine 2 and bis(2‐pyrimidyl)‐1,2,4,5‐tetrazine=bmtz as ligands, the complexes 3=[Ru(acac)2(1)], 4={[Ru(acac)2]2(1)], 5={[Ru(acac)2]2(bmtz)], and 6={[Ru(acac)2]2(2)] were prepared and identified by structure analy...

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Bibliographic Details

Published in:	Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 648; no. 23
Main Authors:	Kaim, Wolfgang, Löw, Isabell, Ringenberg, Mark R., Schwederski, Brigitte, Filippou, Vasileios, Fiedler, Jan
Format:	Journal Article
Language:	English
Published:	Weinheim Wiley Subscription Services, Inc 13.12.2022
Subjects:	Complex formation Crystal structure Crystallization Cyclic voltammetry Diruthenium compounds EPR spectroscopy Ligands Oxidation Spectroelectrochemistry Structural analysis
ISSN:	0044-2313, 1521-3749
Online Access:	Get full text
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