Improved synthesis of perfluorooctylpropyl amine

Graphic Hydrazinolysis of N-perfluorooctylpropyl phthalimide is an easy route to scale up for the title compound. Both the alkylation of potassium phthalimide with perfluorooctylpropyl iodide and the hydrogenolysis of the adduct of perfluoroctyl iodide to N-allyl-phthalimide provide this amine precu...

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Vydáno v:Journal of fluorine chemistry Ročník 125; číslo 7; s. 1143 - 1146
Hlavní autoři: Abulikemu, Abudurexiti, Halász, Gábor, Csámpai, Antal, Gömöry, Ágnes, Rábai, József
Médium: Journal Article
Jazyk:angličtina
Vydáno: LAUSANNE Elsevier B.V 01.07.2004
Elsevier
Témata:
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Dehalogenation
Perfluorooctylpropyl amine
Physical Sciences
Preparation
Science & Technology
Dehalogenation
Preparation
Perfluorooctylpropyl amine
perfluorooctylpropyl amine
dehalogenation
preparation
ISSN:0022-1139, 1873-3328
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Popis
Shrnutí:Graphic Hydrazinolysis of N-perfluorooctylpropyl phthalimide is an easy route to scale up for the title compound. Both the alkylation of potassium phthalimide with perfluorooctylpropyl iodide and the hydrogenolysis of the adduct of perfluoroctyl iodide to N-allyl-phthalimide provide this amine precursor in good yields. The latter procedure, however, has a better atom economy, since it requires only three steps from perfluorooctyl iodide.
ISSN:0022-1139
1873-3328
DOI:10.1016/j.jfluchem.2004.02.006