Titania supported silicotungstic acid: An efficient solid acid catalyst for veratrole acylation

Titania supported silicotungstic acid (STA) with different STA loading (10–25wt%) and calcination temperature (650–750°C) were prepared by wet impregnation method. The catalysts have been represented by a general formula xSTiO2y (where x denotes wt%, S denotes STA and y denotes calcination temperatu...

Celý popis

Uloženo v:
Podrobná bibliografie
Vydáno v:Catalysis communications Ročník 9; číslo 10; s. 2026 - 2029
Hlavní autoři: Waghmare, Nilesh G., Kasinathan, Palraj, Amrute, Amol, Lucas, Nishita, Halligudi, S.B.
Médium: Journal Article
Jazyk:angličtina
Vydáno: Elsevier B.V 10.06.2008
Témata:
Acetic anhydride
Acylation
Silicotungstic acid
Titania
Veratrole
Silicotungstic acid
Veratrole
Titania
Acetic anhydride
Acylation
ISSN:1566-7367, 1873-3905
On-line přístup:Získat plný text
Tagy: Přidat tag
Žádné tagy, Buďte první, kdo vytvoří štítek k tomuto záznamu!
Popis
Shrnutí:Titania supported silicotungstic acid (STA) with different STA loading (10–25wt%) and calcination temperature (650–750°C) were prepared by wet impregnation method. The catalysts have been represented by a general formula xSTiO2y (where x denotes wt%, S denotes STA and y denotes calcination temperature in °C). These catalysts were characterized by techniques such as X-ray diffraction, surface analysis, FTIR–pyridine and TPD–NH3 and were used as heterogeneous solid acid catalysts in the liquid phase acylation of veratrole with acetic anhydride (Ac2O). It was found that 20STiO2700 gave the highest activity in acylation reaction due to its highest acidity.
ISSN:1566-7367
1873-3905
DOI:10.1016/j.catcom.2008.03.043