Charge and spin coupling in copper compounds with hemilabile noninnocent ligands – Ambivalence in three dimensions

[Display omitted] •Coordinative ambivalence of CuI and CuII.•Conjugated noninnocent ligands with optional thioether or selenoether function.•Change of structure and spin coupling patterns through Cu–chalcogen contact interaction.•Experimental and computational analysis.•Three-dimensional ambivalence...

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Bibliographic Details

Published in:	Coordination chemistry reviews Vol. 355; pp. 173 - 179
Main Authors:	Kaim, Wolfgang, Beyer, Katharina, Filippou, Vasileios, Záliš, Stanislav
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 15.01.2018
Subjects:	Copper complexes Electronic structure Hemilabile ligands Noninnocent ligands Oxidation states Electronic structure Noninnocent ligands Hemilabile ligands Oxidation states Copper complexes
ISSN:	0010-8545, 1873-3840
Online Access:	Get full text
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