Condensation reactions assisted by acidic hydrogen bonded hydroxyl groups in solid tin(ii)hydroxychloride

Tin(ii)hydroxychloride is reported as a heterogeneous Broensted acid catalyst. Sn(OH)Cl was synthesized by a precipitation method and characterized by XRD, FT-IR, super(1)H MAS NMR, SEM, TG-DTA and N sub(2) sorption. The acidity measurements of tin(ii)hydroxychloride by FT-IR pyridine adsorption and...

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Vydáno v:RSC advances Ročník 3; číslo 27; s. 10795 - 10800
Hlavní autoři: Marakatti, Vijaykumar S., Shanbhag, Ganapati V., Halgeri, Anand B.
Médium: Journal Article
Jazyk:angličtina
Vydáno: 01.01.2013
Témata:
acidity
adsorption
Bonding
Bronsted acids
Catalysts
catalytic activity
condensation reactions
Condensing
differential thermal analysis
Fourier transform infrared spectroscopy
Hydrogen bonding
moieties
nitrogen
Nuclear magnetic resonance
nuclear magnetic resonance spectroscopy
Precipitation
pyridines
Recycled
scanning electron microscopy
thermogravimetry
tin
Tin dioxide
tin monoxide
X-ray diffraction
ISSN:2046-2069, 2046-2069
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Abstract Tin(ii)hydroxychloride is reported as a heterogeneous Broensted acid catalyst. Sn(OH)Cl was synthesized by a precipitation method and characterized by XRD, FT-IR, super(1)H MAS NMR, SEM, TG-DTA and N sub(2) sorption. The acidity measurements of tin(ii)hydroxychloride by FT-IR pyridine adsorption and super(1)H MAS NMR showed the presence of Broensted acidity. The Broensted acidity can be attributed to strong hydrogen bonding between the -OH and Cl groups. Sn(OH)Cl showed high activity for important condensation reactions such as the Prins condensation, Claisen-Schmidt condensation and ketalization. The catalytic activity of Sn(OH)Cl was compared with that of SnO, SnO sub(2) and Sn sub(2)(OH) sub(2)O. The catalyst was recycled three times with a negligible decrease in activity.
AbstractList Tin(ii)hydroxychloride is reported as a heterogeneous Brønsted acid catalyst. Sn(OH)Cl was synthesized by a precipitation method and characterized by XRD, FT-IR, ¹H MAS NMR, SEM, TG-DTA and N₂ sorption. The acidity measurements of tin(ii)hydroxychloride by FT-IR pyridine adsorption and ¹H MAS NMR showed the presence of Brønsted acidity. The Brønsted acidity can be attributed to strong hydrogen bonding between the –OH and Cl groups. Sn(OH)Cl showed high activity for important condensation reactions such as the Prins condensation, Claisen–Schmidt condensation and ketalization. The catalytic activity of Sn(OH)Cl was compared with that of SnO, SnO₂ and Sn₂(OH)₂O. The catalyst was recycled three times with a negligible decrease in activity.
Tin(ii)hydroxychloride is reported as a heterogeneous Broensted acid catalyst. Sn(OH)Cl was synthesized by a precipitation method and characterized by XRD, FT-IR, super(1)H MAS NMR, SEM, TG-DTA and N sub(2) sorption. The acidity measurements of tin(ii)hydroxychloride by FT-IR pyridine adsorption and super(1)H MAS NMR showed the presence of Broensted acidity. The Broensted acidity can be attributed to strong hydrogen bonding between the -OH and Cl groups. Sn(OH)Cl showed high activity for important condensation reactions such as the Prins condensation, Claisen-Schmidt condensation and ketalization. The catalytic activity of Sn(OH)Cl was compared with that of SnO, SnO sub(2) and Sn sub(2)(OH) sub(2)O. The catalyst was recycled three times with a negligible decrease in activity.
Author Marakatti, Vijaykumar S.
Halgeri, Anand B.
Shanbhag, Ganapati V.
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Cites_doi 10.1039/b313747c
10.1180/minmag.1992.056.383.08
10.1246/bcsj.57.1087
10.1016/S0021-9517(02)00013-1
10.1016/j.apcata.2008.08.020
10.1016/S0926-860X(01)00839-0
10.1016/j.cattod.2012.01.028
10.1016/j.catcom.2008.01.025
10.1016/j.apcata.2010.10.005
10.1016/j.molcata.2007.03.054
10.1016/j.apcata.2009.11.014
10.1039/jr9630001727
10.1016/j.micromeso.2010.07.021
10.1006/jcat.2000.3044
10.1039/b801361f
10.1016/j.catcom.2011.03.034
10.1021/ja01208a032
10.3390/molecules15085258
10.1016/j.molcata.2005.11.036
10.1016/j.cattod.2005.07.049
10.1016/j.catcom.2006.04.002
10.1016/j.matchemphys.2007.04.030
10.1016/j.micromeso.2009.03.003
10.1016/j.ccr.2005.04.031
10.1016/S1387-1811(99)00180-8
10.1016/j.molcata.2003.10.043
10.1039/c2cy20084h
10.1016/j.apcata.2012.11.016
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References Bain (c3ra41152d-(cit6)/*[position()=1]) 1946; 68
Jouen (c3ra41152d-(cit13)/*[position()=1]) 2007; 105
Niu (c3ra41152d-(cit16)/*[position()=1]) 2008
Jadhav (c3ra41152d-(cit7d)/*[position()=1]) 2010; 390
Edwards (c3ra41152d-(cit3)/*[position()=1]) 1992; 56
Alarcón (c3ra41152d-(cit7f)/*[position()=1]) 2009; 122
Pillai (c3ra41152d-(cit5)/*[position()=1]) 2004
Ichiba (c3ra41152d-(cit12)/*[position()=1]) 1984; 57
Hattori (c3ra41152d-(cit2)/*[position()=1]) 2001; 222
Shylesh (c3ra41152d-(cit9d)/*[position()=1]) 2004; 212
Alarcón (c3ra41152d-(cit7a)/*[position()=1]) 2010; 136
Selvaraj (c3ra41152d-(cit7c)/*[position()=1]) 2010; 373
Donaldson (c3ra41152d-(cit11)/*[position()=1]) 1963
Wang (c3ra41152d-(cit8)/*[position()=1]) 2011; 12
Peng (c3ra41152d-(cit1)/*[position()=1]) 2010; 15
Climent (c3ra41152d-(cit9a)/*[position()=1]) 2000; 196
Drexler (c3ra41152d-(cit10a)/*[position()=1]) 2003; 214
Villa de P (c3ra41152d-(cit7b)/*[position()=1]) 2005; 107
Jadhav (c3ra41152d-(cit10c)/*[position()=1]) 2012; 198
Sujandhi (c3ra41152d-(cit10b)/*[position()=1]) 2008; 350
Justus (c3ra41152d-(cit9b)/*[position()=1]) 2008; 9
Kovács (c3ra41152d-(cit15)/*[position()=1]) 2006; 250
Do (c3ra41152d-(cit7h)/*[position()=1]) 2012; 2
Patil (c3ra41152d-(cit7e)/*[position()=1]) 2007; 273
Müller (c3ra41152d-(cit14)/*[position()=1]) 2000; 34
Zhang (c3ra41152d-(cit9c)/*[position()=1]) 2006; 247
Yadav (c3ra41152d-(cit7g)/*[position()=1]) 2006; 7
Marakatti (c3ra41152d-(cit4)/*[position()=1]) 2013; 451
References_xml – start-page: 826
  year: 2004
  ident: c3ra41152d-(cit5)/*[position()=1]
  publication-title: Chem. Commun.
  doi: 10.1039/b313747c
– volume: 56
  start-page: 221
  year: 1992
  ident: c3ra41152d-(cit3)/*[position()=1]
  publication-title: Mineral. Mag.
  doi: 10.1180/minmag.1992.056.383.08
– volume: 57
  start-page: 1087
  year: 1984
  ident: c3ra41152d-(cit12)/*[position()=1]
  publication-title: Bull. Chem. Soc. Jpn.
  doi: 10.1246/bcsj.57.1087
– volume: 214
  start-page: 136
  year: 2003
  ident: c3ra41152d-(cit10a)/*[position()=1]
  publication-title: J. Catal.
  doi: 10.1016/S0021-9517(02)00013-1
– volume: 350
  start-page: 244
  year: 2008
  ident: c3ra41152d-(cit10b)/*[position()=1]
  publication-title: Appl. Catal., A
  doi: 10.1016/j.apcata.2008.08.020
– volume: 222
  start-page: 247
  year: 2001
  ident: c3ra41152d-(cit2)/*[position()=1]
  publication-title: Appl. Catal., A
  doi: 10.1016/S0926-860X(01)00839-0
– volume: 198
  start-page: 98
  year: 2012
  ident: c3ra41152d-(cit10c)/*[position()=1]
  publication-title: Catal. Today
  doi: 10.1016/j.cattod.2012.01.028
– volume: 9
  start-page: 1671
  year: 2008
  ident: c3ra41152d-(cit9b)/*[position()=1]
  publication-title: Catal. Commun.
  doi: 10.1016/j.catcom.2008.01.025
– volume: 390
  start-page: 158
  year: 2010
  ident: c3ra41152d-(cit7d)/*[position()=1]
  publication-title: Appl. Catal., A
  doi: 10.1016/j.apcata.2010.10.005
– volume: 273
  start-page: 39
  year: 2007
  ident: c3ra41152d-(cit7e)/*[position()=1]
  publication-title: J. Mol. Catal. A: Chem.
  doi: 10.1016/j.molcata.2007.03.054
– volume: 373
  start-page: 186
  year: 2010
  ident: c3ra41152d-(cit7c)/*[position()=1]
  publication-title: Appl. Catal., A
  doi: 10.1016/j.apcata.2009.11.014
– start-page: 1727
  year: 1963
  ident: c3ra41152d-(cit11)/*[position()=1]
  publication-title: J. Chem. Soc.
  doi: 10.1039/jr9630001727
– volume: 136
  start-page: 59
  year: 2010
  ident: c3ra41152d-(cit7a)/*[position()=1]
  publication-title: Microporous Mesoporous Mater.
  doi: 10.1016/j.micromeso.2010.07.021
– volume: 196
  start-page: 345
  year: 2000
  ident: c3ra41152d-(cit9a)/*[position()=1]
  publication-title: J. Catal.
  doi: 10.1006/jcat.2000.3044
– start-page: 2803
  year: 2008
  ident: c3ra41152d-(cit16)/*[position()=1]
  publication-title: Chem. Commun.
  doi: 10.1039/b801361f
– volume: 12
  start-page: 1131
  year: 2011
  ident: c3ra41152d-(cit8)/*[position()=1]
  publication-title: Catal. Commun.
  doi: 10.1016/j.catcom.2011.03.034
– volume: 68
  start-page: 638
  year: 1946
  ident: c3ra41152d-(cit6)/*[position()=1]
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja01208a032
– volume: 15
  start-page: 5258
  year: 2010
  ident: c3ra41152d-(cit1)/*[position()=1]
  publication-title: Molecules
  doi: 10.3390/molecules15085258
– volume: 247
  start-page: 130
  year: 2006
  ident: c3ra41152d-(cit9c)/*[position()=1]
  publication-title: J. Mol. Catal. A: Chem.
  doi: 10.1016/j.molcata.2005.11.036
– volume: 107
  start-page: 942
  year: 2005
  ident: c3ra41152d-(cit7b)/*[position()=1]
  publication-title: Catal. Today
  doi: 10.1016/j.cattod.2005.07.049
– volume: 7
  start-page: 889
  year: 2006
  ident: c3ra41152d-(cit7g)/*[position()=1]
  publication-title: Catal. Commun.
  doi: 10.1016/j.catcom.2006.04.002
– volume: 105
  start-page: 189
  year: 2007
  ident: c3ra41152d-(cit13)/*[position()=1]
  publication-title: Mater. Chem. Phys.
  doi: 10.1016/j.matchemphys.2007.04.030
– volume: 122
  start-page: 208
  year: 2009
  ident: c3ra41152d-(cit7f)/*[position()=1]
  publication-title: Microporous Mesoporous Mater.
  doi: 10.1016/j.micromeso.2009.03.003
– volume: 250
  start-page: 710
  year: 2006
  ident: c3ra41152d-(cit15)/*[position()=1]
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/j.ccr.2005.04.031
– volume: 34
  start-page: 281
  year: 2000
  ident: c3ra41152d-(cit14)/*[position()=1]
  publication-title: Microporous Mesoporous Mater.
  doi: 10.1016/S1387-1811(99)00180-8
– volume: 212
  start-page: 219
  year: 2004
  ident: c3ra41152d-(cit9d)/*[position()=1]
  publication-title: J. Mol. Catal. A: Chem.
  doi: 10.1016/j.molcata.2003.10.043
– volume: 2
  start-page: 1417
  year: 2012
  ident: c3ra41152d-(cit7h)/*[position()=1]
  publication-title: Catal. Sci. Technol.
  doi: 10.1039/c2cy20084h
– volume: 451
  start-page: 71
  year: 2013
  ident: c3ra41152d-(cit4)/*[position()=1]
  publication-title: Appl. Catal., A
  doi: 10.1016/j.apcata.2012.11.016
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Snippet Tin(ii)hydroxychloride is reported as a heterogeneous Broensted acid catalyst. Sn(OH)Cl was synthesized by a precipitation method and characterized by XRD,...
Tin(ii)hydroxychloride is reported as a heterogeneous Brønsted acid catalyst. Sn(OH)Cl was synthesized by a precipitation method and characterized by XRD,...
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SubjectTerms acidity
adsorption
Bonding
Bronsted acids
Catalysts
catalytic activity
condensation reactions
Condensing
differential thermal analysis
Fourier transform infrared spectroscopy
Hydrogen bonding
moieties
nitrogen
Nuclear magnetic resonance
nuclear magnetic resonance spectroscopy
Precipitation
pyridines
Recycled
scanning electron microscopy
thermogravimetry
tin
Tin dioxide
tin monoxide
X-ray diffraction
Title Condensation reactions assisted by acidic hydrogen bonded hydroxyl groups in solid tin(ii)hydroxychloride
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