Parameter estimation algorithm for a PEM electrolyzer equivalent circuit model under current ripple conditions

Unknown parameter estimation for electrical models of proton exchange membrane (PEM) electrolyzers is important for optimal hydrogen production and storage in power systems. Algorithms for correctly identifying parameters for different models, including equivalent circuit models (ECM), have been rep...

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Vydáno v:Electric power systems research Ročník 251; s. 112324
Hlavní autoři: Hernández-Gómez, Ángel, Langarica-Cordoba, Diego, Martinez-Rodriguez, Panfilo R., González-Aguilar, Hernán, Guilbert, Damien, Saldivar, Belem
Médium: Journal Article
Jazyk:angličtina
Vydáno: Elsevier B.V 01.02.2026
Elsevier
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ISSN:0378-7796, 1873-2046
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Abstract Unknown parameter estimation for electrical models of proton exchange membrane (PEM) electrolyzers is important for optimal hydrogen production and storage in power systems. Algorithms for correctly identifying parameters for different models, including equivalent circuit models (ECM), have been reported. These are important for analyzing the transient dynamics of the PEM electrolyzer connected to grid-tied power electronics sources. However, no method has been reported to correctly estimate the ECM parameters when subjected to current ripple from power electronics. Current ripple is an important issue requiring further investigations since they are responsible for the accelerated aging of electrolyzers. In this work, an algorithm has been developed to estimate the parameters of an ECM for the electrolyzer voltage under input current ripple. Furthermore, based on the gradient method, this algorithm allows adapting the parameters with the values of the proposed electronic components, i.e., resistors, capacitors, and voltage sources. The proposed algorithm has been validated using two voltage–current databases obtained from a commercial PEM electrolyzer system NMH2 1000. Thus, by efficiently estimating the ECM parameters, the proposed algorithm facilitates the design and construction of power converters coupled to the electrolyzer under current ripple constraints. •ECM parameter estimation for the voltage of a PEM electrolyzer.•Analysis of the effect of current ripples on PEM electrolyzer.•Development of an algorithm to estimate parameters.•Estimation of activation and concentration voltages based on an equivalent circuit.•Application of the gradient method to the ECM under current ripple conditions.
AbstractList Unknown parameter estimation for electrical models of proton exchange membrane (PEM) electrolyzers is important for optimal hydrogen production and storage in power systems. Algorithms for correctly identifying parameters for different models, including equivalent circuit models (ECM), have been reported. These are important for analyzing the transient dynamics of the PEM electrolyzer connected to grid-tied power electronics sources. However, no method has been reported to correctly estimate the ECM parameters when subjected to current ripple from power electronics. Current ripple is an important issue requiring further investigations since they are responsible for the accelerated aging of electrolyzers. In this work, an algorithm has been developed to estimate the parameters of an ECM for the electrolyzer voltage under input current ripple. Furthermore, based on the gradient method, this algorithm allows adapting the parameters with the values of the proposed electronic components, i.e., resistors, capacitors, and voltage sources. The proposed algorithm has been validated using two voltage–current databases obtained from a commercial PEM electrolyzer system NMH2 1000. Thus, by efficiently estimating the ECM parameters, the proposed algorithm facilitates the design and construction of power converters coupled to the electrolyzer under current ripple constraints.
Unknown parameter estimation for electrical models of proton exchange membrane (PEM) electrolyzers is important for optimal hydrogen production and storage in power systems. Algorithms for correctly identifying parameters for different models, including equivalent circuit models (ECM), have been reported. These are important for analyzing the transient dynamics of the PEM electrolyzer connected to grid-tied power electronics sources. However, no method has been reported to correctly estimate the ECM parameters when subjected to current ripple from power electronics. Current ripple is an important issue requiring further investigations since they are responsible for the accelerated aging of electrolyzers. In this work, an algorithm has been developed to estimate the parameters of an ECM for the electrolyzer voltage under input current ripple. Furthermore, based on the gradient method, this algorithm allows adapting the parameters with the values of the proposed electronic components, i.e., resistors, capacitors, and voltage sources. The proposed algorithm has been validated using two voltage–current databases obtained from a commercial PEM electrolyzer system NMH2 1000. Thus, by efficiently estimating the ECM parameters, the proposed algorithm facilitates the design and construction of power converters coupled to the electrolyzer under current ripple constraints. •ECM parameter estimation for the voltage of a PEM electrolyzer.•Analysis of the effect of current ripples on PEM electrolyzer.•Development of an algorithm to estimate parameters.•Estimation of activation and concentration voltages based on an equivalent circuit.•Application of the gradient method to the ECM under current ripple conditions.
ArticleNumber 112324
Author Martinez-Rodriguez, Panfilo R.
González-Aguilar, Hernán
Saldivar, Belem
Hernández-Gómez, Ángel
Langarica-Cordoba, Diego
Guilbert, Damien
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  surname: Hernández-Gómez
  fullname: Hernández-Gómez, Ángel
  email: angel.hernandez@uaslp.mx
  organization: School of Sciences, Universidad Autónoma de San Luis Potosí (UASLP), San Luis Potosí, 78295, San Luis Potosí, Mexico
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  givenname: Diego
  orcidid: 0000-0002-9077-6931
  surname: Langarica-Cordoba
  fullname: Langarica-Cordoba, Diego
  email: dlangaricacordoba@utep.edu
  organization: Department of Electrical and Computer Engineering, The University of Texas at El Paso, TX 79968, USA
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  givenname: Panfilo R.
  orcidid: 0000-0002-9613-805X
  surname: Martinez-Rodriguez
  fullname: Martinez-Rodriguez, Panfilo R.
  email: pamartinez@ieee.org
  organization: School of Sciences, Universidad Autónoma de San Luis Potosí (UASLP), San Luis Potosí, 78295, San Luis Potosí, Mexico
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  givenname: Hernán
  orcidid: 0009-0005-3781-8492
  surname: González-Aguilar
  fullname: González-Aguilar, Hernán
  email: hernan@fc.uaslp.mx
  organization: School of Sciences, Universidad Autónoma de San Luis Potosí (UASLP), San Luis Potosí, 78295, San Luis Potosí, Mexico
– sequence: 5
  givenname: Damien
  orcidid: 0000-0003-4662-3185
  surname: Guilbert
  fullname: Guilbert, Damien
  email: damien.guilbert@univ-lehavre.fr
  organization: GREAH, Université Le Havre Normandie, 76600 Le Havre, France
– sequence: 6
  givenname: Belem
  orcidid: 0000-0002-5150-8635
  surname: Saldivar
  fullname: Saldivar, Belem
  email: belem.saldivar@cinvestav.mx
  organization: Department of Automatic Control, CINVESTAV-IPN, Av. Instituto Politécnico Nacional 2508, Mexico City 07360, Mexico
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Keywords Electrolyzer modeling
Parameter estimator
PEM electrolyzer
Equivalent circuit model
Language English
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Snippet Unknown parameter estimation for electrical models of proton exchange membrane (PEM) electrolyzers is important for optimal hydrogen production and storage in...
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StartPage 112324
SubjectTerms Electric power
Electrolyzer modeling
Engineering Sciences
Equivalent circuit model
Parameter estimator
PEM electrolyzer
Title Parameter estimation algorithm for a PEM electrolyzer equivalent circuit model under current ripple conditions
URI https://dx.doi.org/10.1016/j.epsr.2025.112324
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