Room‐Temperature Wide‐Gap Inorganic Materials with Excellent Plasticity

In general, inorganic non‐metallic materials exhibit brittleness, and achieving plasticity in wide‐gap semiconductors or dielectrics poses an even greater challenge. Historically, silver halides have been suggested to be ductile; however, their deformability under different load modes has not been w...

Celý popis

Uloženo v:
Podrobná bibliografie
Vydáno v:Advanced functional materials Ročník 33; číslo 43
Hlavní autoři: Huang, Haoran, Chen, Heyang, Gao, Zhiqiang, Ma, Yupeng, Zhao, Kunpeng, Wei, Tian‐Ran, Shi, Xun
Médium: Journal Article
Jazyk:angličtina
Vydáno: Hoboken Wiley Subscription Services, Inc 18.10.2023
Témata:
Deformation
Dielectrics
Formability
Inorganic materials
Materials science
Plastic properties
Polycrystals
Room temperature
Silver chloride
Silver halides
ISSN:1616-301X, 1616-3028
On-line přístup:Získat plný text
Tagy: Přidat tag
Žádné tagy, Buďte první, kdo vytvoří štítek k tomuto záznamu!
Popis
Shrnutí:In general, inorganic non‐metallic materials exhibit brittleness, and achieving plasticity in wide‐gap semiconductors or dielectrics poses an even greater challenge. Historically, silver halides have been suggested to be ductile; however, their deformability under different load modes has not been well demonstrated, and the underlying mechanisms are not fully understood. In this study, the authors demonstrate the excellent plasticity of AgCl and AgBr polycrystals at room temperature under tension, bending, compression, and roller pressing. In particular, the rolling reduction rate of AgCl/AgBr exceeds 97%, corresponding to the plastic extensibility from 3600% to 4200%. The metal‐like plasticity and multiple slip systems are attributed to the ionic features, specifically the Coulombic nature of the Ag‐Cl/Br interactions, and the appreciable polarization of the anions. Such less localized diffuse bonding can be readily switched upon atomic gliding, thus ensuring slip without cleavage. This study contributes to the advancement of the understanding and development of wide‐gap plastically deformable inorganic materials for applications in flexible, shape‐conformable high‐power electronics and dielectrics.
Bibliografie:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ISSN:1616-301X
1616-3028
DOI:10.1002/adfm.202306042