Investigation into the surface chemical analysis and luminescent properties of La7O6(BO3)(PO4)2:Dy phosphor

The exploitation of high-quality borophosphate-based phosphor products is currently garnering a significant research focus in solid-state light source. The interest is due to its low-cost and environment-friendly synthesis. In this paper, a new La7O6(BO3)(PO4)2 (LBP):Dy phosphor was developed via si...

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Veröffentlicht in:Ceramics international Jg. 46; H. 6; S. 8483 - 8489
Hauptverfasser: Che, Yi, Zheng, Youkui, Yang, Dan, Fang, Zhenyu, Li, Cheng, Zhu, Jing
Format: Journal Article
Sprache:Englisch
Veröffentlicht: Elsevier Ltd 15.04.2020
Schlagworte:
Borophosphate
Content quenching
Dysprosium
Phosphor
Yellow emission
Borophosphate
Yellow emission
Dysprosium
Phosphor
Content quenching
ISSN:0272-8842, 1873-3956
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Zusammenfassung:The exploitation of high-quality borophosphate-based phosphor products is currently garnering a significant research focus in solid-state light source. The interest is due to its low-cost and environment-friendly synthesis. In this paper, a new La7O6(BO3)(PO4)2 (LBP):Dy phosphor was developed via sintering at 1673 K for 3 h under an air atmosphere. Structural characterization indicates that all of the prepared products are the monoclinic phases with the space group P21/n. A comparison of the surface chemical states of the elemental compositions for the LBP host versus optimal LBP:13%Dy product was conducted via X-ray photoelectron spectroscopy. Optical characterization shows that the Dy-doped products exhibited visible light emissions of Dy3+ from 4F9/2 to 6H15/2, 6H13/2, and 6H11/2 upon exposure to 348 nm near-ultra violet irradiation. The dominant emission (yellow, 576 nm) belongs to the 4F9/2 → 6H13/2 transition. The best Dy content for doping was 13 mol%, and content quenching occurred due to dipole – dipole interaction. The measured decay lifetime and calculated chromatic properties together manifest that the optimal LBP:13%Dy phosphor shows potential as a yellow ingredient in solid-state lighting.
ISSN:0272-8842
1873-3956
DOI:10.1016/j.ceramint.2019.11.243