Electronic Structures and Reactivity Profiles of Aryl Nitrenoid-Bridged Dicopper Complexes

Dicopper complexes templated by dinucleating, pacman dipyrrin ligand scaffolds ((Mes)dmx, (tBu)dmx: dimethylxanthine-bridged, cofacial bis-dipyrrin) were synthesized by deprotonation/metalation with mesitylcopper (CuMes; Mes: mesityl) or by transmetalation with cuprous precursors from the correspond...

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Bibliographic Details
Published in:	Journal of the American Chemical Society Vol. 142; no. 5; pp. 2264 - 2276
Main Authors:	Carsch, Kurtis M., Lukens, James T., DiMucci, Ida M., Iovan, Diana A., Zheng, Shao-Liang, Lancaster, Kyle M., Betley, Theodore A.
Format:	Journal Article
Language:	English
Published:	WASHINGTON Amer Chemical Soc 05.02.2020
Subjects:	Chemistry Chemistry, Multidisciplinary Copper - chemistry Imines - chemistry Models, Molecular Molecular Structure Oxidation-Reduction Physical Sciences Science & Technology X-Ray Absorption Spectroscopy IMIDO COMPLEXES OXIDATION AMINATION METHANE TRANSITION-METAL-COMPLEXES GROUND-STATE DIAMOND CORES CU-A COPPER H BOND FUNCTIONALIZATION
ISSN:	0002-7863, 1520-5126, 1520-5126
Online Access:	Get more information
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