A Synthesis of Alsmaphorazine B Demonstrates the Chemical Feasibility of a New Biogenetic Hypothesis

An N-oxide fragmentation/hydroxylamine oxidation/intramolecular 1,3-dipolar cycloaddition. Cascade, efficiently converted an oxidized congener of akuammicine into the complex, hexacyclic architecture of the alsmaphorazine alkaloids. This dramatic structural Change shows the chemical feasibility of o...

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Vydané v:	Journal of the American Chemical Society Ročník 137; číslo 23; s. 7306 - 7309
Hlavní autori:	Hong, Allen Y., Vanderwal, Christopher D.
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	WASHINGTON Amer Chemical Soc 17.06.2015
Predmet:	Chemistry Chemistry, Multidisciplinary Cyclization Indole Alkaloids - chemical synthesis Indole Alkaloids - chemistry Models, Molecular Molecular Structure Oxidation-Reduction Physical Sciences Science & Technology REARRANGEMENT (+/-)-AKUAMMICINE CONVERSION CYCLOADDITIONS BIOSYNTHESIS ASPIDOSPERMA (+/-)-ECHITAMIDINE (-)-VINDOLINE NORFLUOROCURARINE STRYCHNOS ALKALOIDS
ISSN:	0002-7863, 1520-5126
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