Directed, Palladium(II)-Catalyzed Enantioselective anti-Carboboration of Alkenyl Carbonyl Compounds

A substrate-directed enantioselective anti-carboboration reaction of alkenes has been developed, wherein a carbon-based nucleophile and a boron moiety are installed across the C=C bond through a 5-membered palladacycle intermediate. A preliminary result also shows it is possible to extend this react...

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Vydané v:	ACS catalysis Ročník 9; číslo 4; s. 3260
Hlavní autori:	Liu, Zhen, Li, Xiaohan, Zeng, Tian, Engle, Keary M
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	United States 05.04.2019
Predmet:	MOX ligand carboboration palladium directing group enantioselective catalysis
ISSN:	2155-5435, 2155-5435
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