Directed, Palladium(II)-Catalyzed Enantioselective anti-Carboboration of Alkenyl Carbonyl Compounds

A substrate-directed enantioselective anti-carboboration reaction of alkenes has been developed, wherein a carbon-based nucleophile and a boron moiety are installed across the C=C bond through a 5-membered palladacycle intermediate. A preliminary result also shows it is possible to extend this react...

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Bibliographic Details

Published in:	ACS catalysis Vol. 9; no. 4; p. 3260
Main Authors:	Liu, Zhen, Li, Xiaohan, Zeng, Tian, Engle, Keary M
Format:	Journal Article
Language:	English
Published:	United States 05.04.2019
Subjects:	MOX ligand carboboration palladium directing group enantioselective catalysis
ISSN:	2155-5435, 2155-5435
Online Access:	Get more information
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