Direct Synthesis of Aluminosilicate IWR Zeolite from a Strong Interaction between Zeolite Framework and Organic Template
A large amount of zeolite structures are still not synthetically available or not available in the form of aluminosilicate currently. Despite significant progress in the development of predictive concepts for zeolite synthesis, accessing some of these new materials is still challenging. One example...
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| Published in: | Journal of the American Chemical Society Vol. 141; no. 45; p. 18318 |
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| Main Authors: | , , , , , , , , , , , , , , , , , , |
| Format: | Journal Article |
| Language: | English |
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United States
13.11.2019
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| ISSN: | 1520-5126, 1520-5126 |
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| Abstract | A large amount of zeolite structures are still not synthetically available or not available in the form of aluminosilicate currently. Despite significant progress in the development of predictive concepts for zeolite synthesis, accessing some of these new materials is still challenging. One example is the IWR structure as well. Despite successful synthesis of Ge-based IWR zeolites, direct synthesis of aluminosilicate IWR zeolite is still not successful. In this report we show how a suitable organic structure directing agent (OSDA), through modeling of an OSDA/zeolite cage interaction, could access directly the aluminum-containing IWR structure (denoted as COE-6), which might allow access to new classes of materials and thus open opportunities in valuable chemical applications. The experimental results reveal that the COE-6 zeolites with a SiO
/Al
O
ratio as low as 30 could be obtained. Very interestingly, the COE-6 zeolite has much higher hydrothermal and thermal stabilities than those of the conventional Ge-Al-IWR zeolite. In methanol-to-propylene (MTP) reaction, the COE-6 zeolite exhibits excellent selectivity for propylene, offering a potential catalyst for MTP reaction in the future. |
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| AbstractList | A large amount of zeolite structures are still not synthetically available or not available in the form of aluminosilicate currently. Despite significant progress in the development of predictive concepts for zeolite synthesis, accessing some of these new materials is still challenging. One example is the IWR structure as well. Despite successful synthesis of Ge-based IWR zeolites, direct synthesis of aluminosilicate IWR zeolite is still not successful. In this report we show how a suitable organic structure directing agent (OSDA), through modeling of an OSDA/zeolite cage interaction, could access directly the aluminum-containing IWR structure (denoted as COE-6), which might allow access to new classes of materials and thus open opportunities in valuable chemical applications. The experimental results reveal that the COE-6 zeolites with a SiO
/Al
O
ratio as low as 30 could be obtained. Very interestingly, the COE-6 zeolite has much higher hydrothermal and thermal stabilities than those of the conventional Ge-Al-IWR zeolite. In methanol-to-propylene (MTP) reaction, the COE-6 zeolite exhibits excellent selectivity for propylene, offering a potential catalyst for MTP reaction in the future. A large amount of zeolite structures are still not synthetically available or not available in the form of aluminosilicate currently. Despite significant progress in the development of predictive concepts for zeolite synthesis, accessing some of these new materials is still challenging. One example is the IWR structure as well. Despite successful synthesis of Ge-based IWR zeolites, direct synthesis of aluminosilicate IWR zeolite is still not successful. In this report we show how a suitable organic structure directing agent (OSDA), through modeling of an OSDA/zeolite cage interaction, could access directly the aluminum-containing IWR structure (denoted as COE-6), which might allow access to new classes of materials and thus open opportunities in valuable chemical applications. The experimental results reveal that the COE-6 zeolites with a SiO2/Al2O3 ratio as low as 30 could be obtained. Very interestingly, the COE-6 zeolite has much higher hydrothermal and thermal stabilities than those of the conventional Ge-Al-IWR zeolite. In methanol-to-propylene (MTP) reaction, the COE-6 zeolite exhibits excellent selectivity for propylene, offering a potential catalyst for MTP reaction in the future.A large amount of zeolite structures are still not synthetically available or not available in the form of aluminosilicate currently. Despite significant progress in the development of predictive concepts for zeolite synthesis, accessing some of these new materials is still challenging. One example is the IWR structure as well. Despite successful synthesis of Ge-based IWR zeolites, direct synthesis of aluminosilicate IWR zeolite is still not successful. In this report we show how a suitable organic structure directing agent (OSDA), through modeling of an OSDA/zeolite cage interaction, could access directly the aluminum-containing IWR structure (denoted as COE-6), which might allow access to new classes of materials and thus open opportunities in valuable chemical applications. The experimental results reveal that the COE-6 zeolites with a SiO2/Al2O3 ratio as low as 30 could be obtained. Very interestingly, the COE-6 zeolite has much higher hydrothermal and thermal stabilities than those of the conventional Ge-Al-IWR zeolite. In methanol-to-propylene (MTP) reaction, the COE-6 zeolite exhibits excellent selectivity for propylene, offering a potential catalyst for MTP reaction in the future. |
| Author | Bao, Xinhe Wu, Qinming Yokoi, Toshiyuki Ma, Yanhang Zhang, Guanqun Marler, Bernd Hong, Xin De Vos, Dirk E Zheng, Anmin Chen, Wei Zhu, Qiuyan Xiao, Feng-Shou Parvulescu, Andrei-Nicolae Han, Shichao Lei, Chi Meng, Xiangju Müller, Ulrich Zhang, Weiping Kolb, Ute |
| Author_xml | – sequence: 1 givenname: Xin surname: Hong fullname: Hong, Xin organization: Department of Chemistry , Zhejiang University , Hangzhou 310028 , People's Republic of China – sequence: 2 givenname: Wei orcidid: 0000-0002-8955-9497 surname: Chen fullname: Chen, Wei organization: State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, National Center for Magnetic Resonance in Wuhan, Key Laboratory of Magnetic Resonance in Biological Systems , Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences , Wuhan 430071 , People's Republic of China – sequence: 3 givenname: Guanqun surname: Zhang fullname: Zhang, Guanqun organization: School of Physical Science and Technology , ShanghaiTech University , Shanghai 201210 , People's Republic of China – sequence: 4 givenname: Qinming surname: Wu fullname: Wu, Qinming organization: Department of Chemistry , Zhejiang University , Hangzhou 310028 , People's Republic of China – sequence: 5 givenname: Chi surname: Lei fullname: Lei, Chi organization: Department of Chemistry , Zhejiang University , Hangzhou 310028 , People's Republic of China – sequence: 6 givenname: Qiuyan surname: Zhu fullname: Zhu, Qiuyan organization: Department of Chemistry , Zhejiang University , Hangzhou 310028 , People's Republic of China – sequence: 7 givenname: Xiangju orcidid: 0000-0001-8740-2755 surname: Meng fullname: Meng, Xiangju organization: Department of Chemistry , Zhejiang University , Hangzhou 310028 , People's Republic of China – sequence: 8 givenname: Shichao surname: Han fullname: Han, Shichao organization: Department of Chemistry , Zhejiang University , Hangzhou 310028 , People's Republic of China – sequence: 9 givenname: Anmin orcidid: 0000-0001-7115-6510 surname: Zheng fullname: Zheng, Anmin organization: State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, National Center for Magnetic Resonance in Wuhan, Key Laboratory of Magnetic Resonance in Biological Systems , Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences , Wuhan 430071 , People's Republic of China – sequence: 10 givenname: Yanhang surname: Ma fullname: Ma, Yanhang organization: School of Physical Science and Technology , ShanghaiTech University , Shanghai 201210 , People's Republic of China – sequence: 11 givenname: Andrei-Nicolae surname: Parvulescu fullname: Parvulescu, Andrei-Nicolae organization: BASF SE , GCC/PZ, Ludwigshafen 67056 , Germany – sequence: 12 givenname: Ulrich surname: Müller fullname: Müller, Ulrich organization: BASF SE , GCC/PZ, Ludwigshafen 67056 , Germany – sequence: 13 givenname: Weiping orcidid: 0000-0003-1227-9769 surname: Zhang fullname: Zhang, Weiping organization: State Key Laboratory of Fine Chemicals , Dalian University of Technology , Dalian 116012 , People's Republic of China – sequence: 14 givenname: Toshiyuki surname: Yokoi fullname: Yokoi, Toshiyuki organization: Chemical Resources Laboratory , Tokyo Institute of Technology , Yokohama 226-8503 , Japan – sequence: 15 givenname: Xinhe orcidid: 0000-0001-9404-6429 surname: Bao fullname: Bao, Xinhe organization: State Key Laboratory of Catalysis , Dalian Institute of Chemical Physics , Dalian 116023 , People's Republic of China – sequence: 16 givenname: Bernd surname: Marler fullname: Marler, Bernd organization: Department of Geology, Mineralogy and Geophysics , Ruhr University Bochum , Bochum 44780 , Germany – sequence: 17 givenname: Dirk E surname: De Vos fullname: De Vos, Dirk E organization: Centre for Surface Chemistry and Catalysis , KU Leuven , Kasteelpark Arenberg 23 , Leuven 3001 , Belgium – sequence: 18 givenname: Ute surname: Kolb fullname: Kolb, Ute organization: Institute of Inorganic Chemistry and Analytical Chemistry , Johannes Gutenberg University Mainz , Mainz 555128 , Germany – sequence: 19 givenname: Feng-Shou orcidid: 0000-0001-9744-3067 surname: Xiao fullname: Xiao, Feng-Shou organization: Department of Chemistry , Zhejiang University , Hangzhou 310028 , People's Republic of China |
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| Title | Direct Synthesis of Aluminosilicate IWR Zeolite from a Strong Interaction between Zeolite Framework and Organic Template |
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