Selective recovery of dynamic guest structure in a nanoporous prussian blue through in situ X-ray diffraction: a differential pair distribution function analysis
We use in situ X-ray diffraction to obtain data suitable for differential PDF analysis, providing unique insight into the structure of weakly bound, dynamic N2 molecules in the Prussian blue system Mn3[Co(CN)6]2.x{N2}. The differential PDF shows a distributed orientation of N2 molecules constrained...
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| Vydané v: | Journal of the American Chemical Society Ročník 127; číslo 32; s. 11232 |
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| Hlavní autori: | , , |
| Médium: | Journal Article |
| Jazyk: | English |
| Vydavateľské údaje: |
United States
17.08.2005
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| ISSN: | 0002-7863 |
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| Shrnutí: | We use in situ X-ray diffraction to obtain data suitable for differential PDF analysis, providing unique insight into the structure of weakly bound, dynamic N2 molecules in the Prussian blue system Mn3[Co(CN)6]2.x{N2}. The differential PDF shows a distributed orientation of N2 molecules constrained to sites centered about the (1/4,1/4,1/4) positions within the pores. The results show a subtle response of the framework to guest loading which corresponds principally to the perturbation of the Mn ion coordination. |
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| Bibliografia: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ISSN: | 0002-7863 |
| DOI: | 10.1021/ja053266k |