Redox- and pH-Responsive Orthogonal Supramolecular Self-Assembly: An Ensemble Displaying Molecular Switching Characteristics

Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P 1) and phenyl C61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates...

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Published in:Journal of the American Chemical Society Vol. 137; no. 51; p. 16038
Main Authors: Kim, Dong Sub, Chang, Jinho, Leem, Soojung, Park, Jung Su, Thordarson, Pall, Sessler, Jonathan L
Format: Journal Article
Language:English
Published: United States 30.12.2015
ISSN:1520-5126, 1520-5126
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Abstract Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P 1) and phenyl C61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates self-assembly of the monomers via a molecular switching event. This results in the formation of materials that may be disaggregated via the addition of an organic acid or electrolysis.
AbstractList Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P 1) and phenyl C61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates self-assembly of the monomers via a molecular switching event. This results in the formation of materials that may be disaggregated via the addition of an organic acid or electrolysis.
Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P 1) and phenyl C61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates self-assembly of the monomers via a molecular switching event. This results in the formation of materials that may be disaggregated via the addition of an organic acid or electrolysis.Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P 1) and phenyl C61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates self-assembly of the monomers via a molecular switching event. This results in the formation of materials that may be disaggregated via the addition of an organic acid or electrolysis.
Author Sessler, Jonathan L
Chang, Jinho
Leem, Soojung
Park, Jung Su
Kim, Dong Sub
Thordarson, Pall
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  givenname: Dong Sub
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  organization: Department of Chemistry, The University of Texas at Austin , 105 East 24th Street, Stop A5300, Austin, Texas 78712-1224, United States
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  givenname: Jinho
  surname: Chang
  fullname: Chang, Jinho
  organization: Department of Chemistry, Sungshin Women's University , 55 Dobong-ro, 76 ga-gil, Gangbuk-gu, Seoul 142-732, Republic of Korea
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  givenname: Soojung
  surname: Leem
  fullname: Leem, Soojung
  organization: Department of Chemistry, The University of Texas at Austin , 105 East 24th Street, Stop A5300, Austin, Texas 78712-1224, United States
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  givenname: Jung Su
  surname: Park
  fullname: Park, Jung Su
  organization: Department of Chemistry, Sookmyung Women's University , Seoul 140-742, Korea
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  fullname: Thordarson, Pall
  organization: School of Chemistry, The University of New South Wales , Sydney, New South Wales 2052, Australia
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  givenname: Jonathan L
  surname: Sessler
  fullname: Sessler, Jonathan L
  organization: Department of Chemistry, The University of Texas at Austin , 105 East 24th Street, Stop A5300, Austin, Texas 78712-1224, United States
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Snippet Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P 1) and phenyl C61 butyric acid (PCBA...
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Title Redox- and pH-Responsive Orthogonal Supramolecular Self-Assembly: An Ensemble Displaying Molecular Switching Characteristics
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