TAPC-promoted oxidation of sulfides and deoxygenation of sulfoxides

1,3,5-Triazo-2,4,6-triphosphorine-2,2,4,4,6,6-tetrachloride (TAPC) was found to be an efficient promoter for the oxidation of sulfides and deoxygenation of sulfoxides. Excellent yields, short reaction time, easy and quick isolation of the products, solvent-free process, and excellent chemoselectivit...

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Bibliographic Details
Published in:Journal of organic chemistry Vol. 75; no. 18; p. 6208
Main Authors: Bahrami, Kiumars, Khodaei, Mohammad M, Sheikh Arabi, Mehdi
Format: Journal Article
Language:English
Published: United States 17.09.2010
Subjects:
Azo Compounds - chemistry
Molecular Structure
Oxidation-Reduction
Stereoisomerism
Sulfides - chemistry
Sulfoxides - chemistry
ISSN:1520-6904, 1520-6904
Online Access:Get more information
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Summary:1,3,5-Triazo-2,4,6-triphosphorine-2,2,4,4,6,6-tetrachloride (TAPC) was found to be an efficient promoter for the oxidation of sulfides and deoxygenation of sulfoxides. Excellent yields, short reaction time, easy and quick isolation of the products, solvent-free process, and excellent chemoselectivity are the main advantages of this procedure.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1520-6904
1520-6904
DOI:10.1021/jo1011784