TAPC-promoted oxidation of sulfides and deoxygenation of sulfoxides

1,3,5-Triazo-2,4,6-triphosphorine-2,2,4,4,6,6-tetrachloride (TAPC) was found to be an efficient promoter for the oxidation of sulfides and deoxygenation of sulfoxides. Excellent yields, short reaction time, easy and quick isolation of the products, solvent-free process, and excellent chemoselectivit...

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Vydáno v:Journal of organic chemistry Ročník 75; číslo 18; s. 6208
Hlavní autoři: Bahrami, Kiumars, Khodaei, Mohammad M, Sheikh Arabi, Mehdi
Médium: Journal Article
Jazyk:angličtina
Vydáno: United States 17.09.2010
Témata:
Azo Compounds - chemistry
Molecular Structure
Oxidation-Reduction
Stereoisomerism
Sulfides - chemistry
Sulfoxides - chemistry
ISSN:1520-6904, 1520-6904
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Shrnutí:1,3,5-Triazo-2,4,6-triphosphorine-2,2,4,4,6,6-tetrachloride (TAPC) was found to be an efficient promoter for the oxidation of sulfides and deoxygenation of sulfoxides. Excellent yields, short reaction time, easy and quick isolation of the products, solvent-free process, and excellent chemoselectivity are the main advantages of this procedure.
Bibliografie:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1520-6904
1520-6904
DOI:10.1021/jo1011784