Oxidative Carbon-Carbon Bond Formation via Allyldimethylsilyl Enol Ethers

A method for the oxidative alkylation of ketones through intramolecular allyl-group transfer within preformed allyldimethylsilyl enol ethers Is reported. A number of examples are detailed, including a study into the effects of resident sterocenters within cyclic enol ethers.

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Bibliographic Details
Published in:	Organic letters Vol. 11; no. 23; pp. 5550 - 5553
Main Authors:	Konkol, Leah C., Jones, Brian T., Thomson, Regan J.
Format:	Journal Article
Language:	English
Published:	WASHINGTON Amer Chemical Soc 03.12.2009
Subjects:	Alkylation Catalysis Chemistry Chemistry, Organic Combinatorial Chemistry Techniques Ethers - chemistry Ketones - chemical synthesis Ketones - chemistry Molecular Structure Organosilicon Compounds - chemistry Oxidation-Reduction Physical Sciences Science & Technology CATION RADICALS SOLVENT-DEPENDENT CHEMOSELECTIVITIES COUPLING REACTIONS ALLYLATION SILICON CERIC AMMONIUM-NITRATE ALLYLTRIMETHYLSILANE
ISSN:	1523-7060, 1523-7052, 1523-7052
Online Access:	Get more information
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