Oxidative Carbon-Carbon Bond Formation via Allyldimethylsilyl Enol Ethers

A method for the oxidative alkylation of ketones through intramolecular allyl-group transfer within preformed allyldimethylsilyl enol ethers Is reported. A number of examples are detailed, including a study into the effects of resident sterocenters within cyclic enol ethers.

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Bibliographische Detailangaben
Veröffentlicht in:Organic letters Jg. 11; H. 23; S. 5550 - 5553
Hauptverfasser: Konkol, Leah C., Jones, Brian T., Thomson, Regan J.
Format: Journal Article
Sprache:Englisch
Veröffentlicht: WASHINGTON Amer Chemical Soc 03.12.2009
Schlagworte:
Alkylation
Catalysis
Chemistry
Chemistry, Organic
Combinatorial Chemistry Techniques
Ethers - chemistry
Ketones - chemical synthesis
Ketones - chemistry
Molecular Structure
Organosilicon Compounds - chemistry
Oxidation-Reduction
Physical Sciences
Science & Technology
CATION RADICALS
SOLVENT-DEPENDENT CHEMOSELECTIVITIES
COUPLING REACTIONS
ALLYLATION
SILICON
CERIC AMMONIUM-NITRATE
ALLYLTRIMETHYLSILANE
ISSN:1523-7060, 1523-7052, 1523-7052
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Zusammenfassung:A method for the oxidative alkylation of ketones through intramolecular allyl-group transfer within preformed allyldimethylsilyl enol ethers Is reported. A number of examples are detailed, including a study into the effects of resident sterocenters within cyclic enol ethers.
Bibliographie:NIH RePORTER
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1523-7060
1523-7052
1523-7052
DOI:10.1021/ol902400q