Organosilicon Radicals with Si-H and Si-Me Bonds from Commodity Precursors

The cyclic alkyl(amino) carbene (cAAC) stabilized biradicals of composition (cAAC) SiH (1), (cAAC)SiMe -SiMe (cAAC) (2), and (cAAC)SiMeCl-SiMeCl(cAAC) (3) have been isolated as molecular species. All the compounds are stable at room temperature for more than 6 months under inert conditions in the so...

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Vydané v:	Journal of the American Chemical Society Ročník 139; číslo 32; s. 11028
Hlavní autori:	Kundu, Subrata, Samuel, Prinson P, Sinhababu, Soumen, Luebben, Anna V, Dittrich, Birger, Andrada, Diego M, Frenking, Gernot, Stückl, A Claudia, Schwederski, Brigitte, Paretzki, Alexa, Kaim, Wolfgang, Roesky, Herbert W
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	United States 16.08.2017
ISSN:	1520-5126, 1520-5126
On-line prístup:	Zistit podrobnosti o prístupe
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