Ruthenium Stilbenyl and Diruthenium Distyrylethene Complexes: Aspects of Electron Delocalization and Electrocatalyzed Isomerization of the Z-Isomer

Regio- and stereoselective insertion of the terminal ethynyl functions of 4-ethynylstilbene, the E and Z isomers of 4,4'-bis(ethynylphenyl)ethene and a backbone-rigidified cyclohexenyl derivative of the Z. isomer into the Ru-H bond of the complex RuClH(CO)((PPr3)-Pr-i)(2) provides the correspon...

Full description

Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 134; no. 40; pp. 16671 - 16692
Main Authors:	Linseis, Michael, Zalis, Stanislav, Zabel, Manfred, Winter, Rainer F.
Format:	Journal Article
Language:	English
Published:	WASHINGTON Amer Chemical Soc 10.10.2012
Subjects:	Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology VIBRATIONAL TIME-SCALE CRYSTAL-STRUCTURE MIXED-VALENCE STATE AB-INITIO RADICAL CATIONS ABSORPTION-SPECTRA CYCLIC VOLTAMMETRY CHARGE-TRANSFER RESONANCE RAMAN CIS-TRANS-ISOMERIZATION
ISSN:	0002-7863, 1520-5126, 1520-5126
Online Access:	Get more information
Tags:	Add Tag No Tags, Be the first to tag this record!