A five-center redox system: molecular coupling of two noninnocent imino-o-benzoquinonato-ruthenium functions through a pi acceptor bridge

Combining the concepts of noninnocent behavior of metal/ligand entities and the coupling of redox-active moieties via an electronically mediating bridge led to the synthesis and the structural, electrochemical, and spectroscopic characterization of [Cl(Q)Ru(mu-tppz)Ru(Q)Cl](n) where Q(o) is 4,6-di-t...

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Bibliographic Details
Published in:Journal of the American Chemical Society Vol. 131; no. 25; p. 8895
Main Authors: Das, Atanu Kumar, Sarkar, Biprajit, Fiedler, Jan, Zális, Stanislav, Hartenbach, Ingo, Strobel, Sabine, Lahiri, Goutam Kumar, Kaim, Wolfgang
Format: Journal Article
Language:English
Published: United States 01.07.2009
ISSN:1520-5126, 1520-5126
Online Access:Get more information
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