Synthesis, structural, and magnetic characterization of linear and bent geometry cobalt(II) and nickel(II) amido complexes: evidence of very large spin-orbit coupling effects in rigorously linear coordinated Co2

The complexes M(II){N(H)Ar(Pr(i)(6))}(2) (M = Co, 1 or Ni, 2; Ar(Pr(i)(6)) = C(6)H(3)-2,6(C(6)H(2)-2,4,6-Pr(i)(3))(2)), which have rigorously linear, N-M-N = 180°, metal coordination, and M(II){N(H)Ar(Me(6))}(2) (M = Co, 3 or Ni, 4; Ar(Me(6)) = C(6)H(3)-2,6(C(6)H(2)-2,4,6-Me(3))(2)), which have bent...

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Vydané v:	Inorganic chemistry Ročník 51; číslo 6; s. 3366
Hlavní autori:	Bryan, Aimee M, Merrill, W Alexander, Reiff, William M, Fettinger, James C, Power, Philip P
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	United States 19.03.2012
ISSN:	1520-510X, 1520-510X
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