At the Borderline between Metal-Metal Mixed Valency and a Radical Bridge Situation: Four Charge States of a Diruthenium Complex with a Redox-Active Bis( mer-tridentate) Ligand

The complex ions [L Ru(μ,η :η -BL)RuL ] (1 , L = 4,4',4″-tri- tert-butyl-2,6,2',6″-terpyridine and H BL = 1,2-bis(salicyloyl)hydrazide(2-)) were isolated with PF or ClO counterions ( n = 1) and as bis(hexafluorophosphate) ( n = 2). Structural, electrochemical, and spectroscopic characteriz...

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Bibliographic Details

Published in:	Inorganic chemistry Vol. 57; no. 7; p. 3983
Main Authors:	Mondal, Sudipta, Schwederski, Brigitte, Frey, Wolfgang, Fiedler, Jan, Záliš, Stanislav, Kaim, Wolfgang
Format:	Journal Article
Language:	English
Published:	United States 02.04.2018
ISSN:	1520-510X, 1520-510X
Online Access:	Get more information
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