Flexibility of an Open Indenyl Ligand in Iron(II) Complexes

[FeI2(thf)(2)] was sequentially treated with Li(C5Me5) and the potassium salt of the phenylmethallyl ("open indenyl") ligand oIndme, leading to selective formation of the half-open ferrocene [(eta(5)-C5Me5)Fe(eta(5)-oInd(Me))] (1). A variable-temperature NMR study revealed a barrier of ca....

Full description

Saved in:
Bibliographic Details
Published in:Organometallics Vol. 31; no. 12; pp. 4480 - 4494
Main Authors: Gloeckner, Andreas, Bannenberg, Thomas, Ibrom, Kerstin, Daniliuc, Constantin G., Freytag, Matthias, Jones, Peter G., Walter, Marc D., Tamm, Matthias
Format: Journal Article
Language:English
Published: WASHINGTON Amer Chemical Soc 25.06.2012
Subjects:
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
PENTADIENYL COMPLEXES
SANDWICH COMPLEXES
RING-SLIPPAGE
TRANSITION-METAL-COMPLEXES
HAPTOTROPIC SHIFTS
ORGANOMETALLIC COMPLEXES
PHOSPHINE CHEMISTRY
SUBSTITUTION-REACTIONS
HALF-OPEN METALLOCENES
ELECTRONIC-STRUCTURE
ISSN:0276-7333, 1520-6041
Online Access:Get more information
Tags: Add Tag
No Tags, Be the first to tag this record!
Abstract [FeI2(thf)(2)] was sequentially treated with Li(C5Me5) and the potassium salt of the phenylmethallyl ("open indenyl") ligand oIndme, leading to selective formation of the half-open ferrocene [(eta(5)-C5Me5)Fe(eta(5)-oInd(Me))] (1). A variable-temperature NMR study revealed a barrier of ca. 12 kcal mol(-1) for the rotation of the phenyl group. The apparent lability and susceptibility of the oIndme ligand in 1 to undergo PIS 113 interconversion allowed the preparation of the complexes [(eta(5)-C5Me5)Fe(eta(3)-oInd(Me))(L)] (2, L = CO; 3, L = IMe; 4, L = PMe3) by addition of carbon monoxide, 1,3,4,5-tetramethylimidazolin-2-ylidene (IMe), and trimethylphosphine, respectively. The eta(3)-bound phenylmethallyl ligand in these complexes initially adopts an anti orientation with regard to the relative positions of the phenyl and methyl substituents, followed by anti-to-syn isomerization. For L = CO, both isomers could be isolated, and the conversion of anti-2 into syn-2 was monitored by NMR spectroscopy at 35, 50, 65, and 80 degrees C, affording an enthalpy of activation of Delta H double dagger = 24(1) kcal mol(-1) for this equilibrium reaction. On the basis of DFT calculations, a mechanism is proposed that proceeds via consecutive eta(3)-eta(1)-eta(3) interconversions and involves eta(3)-benzyl intermediates. In contrast, rapid equilibration was observed for L = IMe and PMe3. Addition of 1,2-bis(dimethylphosphino)ethane (dmpe) to 1 gave (eta(5)-C5Me5)Fe(eta(1)-oInd(Me))(dmpe)] (5), containing the oIndme ligand bound in an eta(1)-allyl fashion, eta(5)-to-eta(3) hapticity interconversion was also observed upon reaction of 1 with methyl iodide and CH2Cl2, which formed the Fe(III) complexes [(eta(5)-C5Me5)Fe(eta(3)-oInd(Me))(X)] (6, X = 1; 7, X = Cl); solid-state magnetic susceptibility measurements on 6 revealed an S = 1/2 ground state. The mixed indenyl open indenyl complex [(eta(5)-Ind")Fe(eta(3)-oInd(Me))(CO)] (9, Ind '' = 1,3-di(tert-butyl)indenyl) was isolated from the stepwise reaction of [FeI2(thf)2] with Na(Ind ''), K(oInd(Me)), and CO. The molecular structures of 1, anti-2, syn-2, syn-3, 5, syn-6, syn-7, and syn-9 were established by single-crystal X-ray diffraction.
AbstractList [FeI2(thf)(2)] was sequentially treated with Li(C5Me5) and the potassium salt of the phenylmethallyl ("open indenyl") ligand oIndme, leading to selective formation of the half-open ferrocene [(eta(5)-C5Me5)Fe(eta(5)-oInd(Me))] (1). A variable-temperature NMR study revealed a barrier of ca. 12 kcal mol(-1) for the rotation of the phenyl group. The apparent lability and susceptibility of the oIndme ligand in 1 to undergo PIS 113 interconversion allowed the preparation of the complexes [(eta(5)-C5Me5)Fe(eta(3)-oInd(Me))(L)] (2, L = CO; 3, L = IMe; 4, L = PMe3) by addition of carbon monoxide, 1,3,4,5-tetramethylimidazolin-2-ylidene (IMe), and trimethylphosphine, respectively. The eta(3)-bound phenylmethallyl ligand in these complexes initially adopts an anti orientation with regard to the relative positions of the phenyl and methyl substituents, followed by anti-to-syn isomerization. For L = CO, both isomers could be isolated, and the conversion of anti-2 into syn-2 was monitored by NMR spectroscopy at 35, 50, 65, and 80 degrees C, affording an enthalpy of activation of Delta H double dagger = 24(1) kcal mol(-1) for this equilibrium reaction. On the basis of DFT calculations, a mechanism is proposed that proceeds via consecutive eta(3)-eta(1)-eta(3) interconversions and involves eta(3)-benzyl intermediates. In contrast, rapid equilibration was observed for L = IMe and PMe3. Addition of 1,2-bis(dimethylphosphino)ethane (dmpe) to 1 gave (eta(5)-C5Me5)Fe(eta(1)-oInd(Me))(dmpe)] (5), containing the oIndme ligand bound in an eta(1)-allyl fashion, eta(5)-to-eta(3) hapticity interconversion was also observed upon reaction of 1 with methyl iodide and CH2Cl2, which formed the Fe(III) complexes [(eta(5)-C5Me5)Fe(eta(3)-oInd(Me))(X)] (6, X = 1; 7, X = Cl); solid-state magnetic susceptibility measurements on 6 revealed an S = 1/2 ground state. The mixed indenyl open indenyl complex [(eta(5)-Ind")Fe(eta(3)-oInd(Me))(CO)] (9, Ind '' = 1,3-di(tert-butyl)indenyl) was isolated from the stepwise reaction of [FeI2(thf)2] with Na(Ind ''), K(oInd(Me)), and CO. The molecular structures of 1, anti-2, syn-2, syn-3, 5, syn-6, syn-7, and syn-9 were established by single-crystal X-ray diffraction.
Author Ibrom, Kerstin
Daniliuc, Constantin G.
Tamm, Matthias
Walter, Marc D.
Gloeckner, Andreas
Jones, Peter G.
Bannenberg, Thomas
Freytag, Matthias
Author_xml – sequence: 1
  givenname: Andreas
  surname: Gloeckner
  fullname: Gloeckner, Andreas
  organization: Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany
– sequence: 2
  givenname: Thomas
  surname: Bannenberg
  fullname: Bannenberg, Thomas
  organization: Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany
– sequence: 3
  givenname: Kerstin
  surname: Ibrom
  fullname: Ibrom, Kerstin
  organization: Tech Univ Carolo Wilhelmina Braunschweig, NMR Lab, Inst Chem, D-38106 Braunschweig, Germany
– sequence: 4
  givenname: Constantin G.
  orcidid: 0000-0002-6709-3673
  surname: Daniliuc
  fullname: Daniliuc, Constantin G.
  organization: Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany
– sequence: 5
  givenname: Matthias
  surname: Freytag
  fullname: Freytag, Matthias
  organization: Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany
– sequence: 6
  givenname: Peter G.
  surname: Jones
  fullname: Jones, Peter G.
  organization: Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany
– sequence: 7
  givenname: Marc D.
  orcidid: 0000-0002-4682-8749
  surname: Walter
  fullname: Walter, Marc D.
  email: mwalter@tu-bs.de
  organization: Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany
– sequence: 8
  givenname: Matthias
  orcidid: 0000-0002-5364-0357
  surname: Tamm
  fullname: Tamm, Matthias
  email: m.tamm@tu-bs.de
  organization: Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany
BookMark eNqNj91KxDAUhIOsYHf1wjfIpSLVk5P-JHglxdXCwt7o9ZI0pxJpk9JWdN_eij6AMDDDwDcwa7YKMRBjlwJuBaC4i70EWKRPWCJyhLSATKxYAlgWaSmlPGPraXoHgKKUmLD7bUdf3vrOz0ceW24C3w8UeB0chWPHd_7NBMf90owxXNX1Na9iPywQTefstDXdRBd_vmGv28eX6jnd7Z_q6mGXGlT5nCIQyYaKxrpGOmmNVqYQyqCxbWaz0jrXaGm1RnIlmlxjm4NCMEpIyjKNG6Z-dz_JxnZqPIWGDsPoezMeD_DzN8-VWgKIrPKzmX0MVfwI84Le_B_Fb0gfXhI
Cites_doi 10.1021/om900754h
10.1021/ar700111a
10.1021/om100840r
10.1021/om000195j
10.1016/SO065-3055(07)55003-3
10.1021/om700886k
10.1021/ja8062343
10.1016/j.ica.2005.09.007
10.1039/b207447h
10.1039/c1dt11436k
10.1002/zaac.200300263
10.1016/j.ica.2006.05.010
10.1016/j.ica.2010.06.049
10.1021/om060444p
10.1039/b209975f
10.1039/c1dt00010a
10.1021/om800922j
10.1021/ja017015x
10.1002/chem.200500179
10.1021/om7010613
10.1016/S0022-328X(03)00596-5
10.1021/ja077334+
10.1021/om2007166
10.1021/om020779g
10.1021/om000589a
10.1107/S2053229614024218
10.1021/om049256u
10.1039/c1nj20399a
10.1021/om050161h
10.1016/j.ccr.2006.10.004
10.1021/om020789h
10.1021/om0609564
10.1021/om900870j
10.1039/c1sc00413a
10.1021/ja012390a
10.1002/ejic.200500812
10.1039/c1cc14576b
10.1021/ja801466t
10.1021/om2011326
10.1021/om020680+
10.1016/j.jorganchem.2004.05.041
10.1021/om7012327
10.1016/J.JORGANCHEM.2009.01.055
10.1021/om034056o
10.1021/om058044+
10.1021/om060100z
10.1002/chem.201003288
10.1039/c1cc11697e
10.1021/ja710568d
10.1039/c2cc18021a
10.1039/c2dt12132h
10.1021/om010793d
10.1021/om010203b
10.1021/om100361a
10.1021/om701277p
10.1021/om900456s
10.1002/anie.200462153
10.1016/j.jorganchem.2005.03.036
10.1021/om7012315
10.1002/ejic.200300359
10.1021/ic300129z
10.1016/j.ccr.2005.11.002
ContentType Journal Article
DBID 17B
1KM
BLEPL
DTL
EGQ
GKHJH
DOI 10.1021/om3003009
DatabaseName Web of Knowledge
Index Chemicus
Web of Science Core Collection
Science Citation Index Expanded
Web of Science Primary (SCIE, SSCI & AHCI)
Web of Science - Science Citation Index Expanded - 2012
DatabaseTitle Web of Science
DatabaseTitleList Web of Science
Database_xml – sequence: 1
  dbid: 1KM
  name: Index Chemicus
  url: https://www.webofscience.com/wos/woscc/search-with-editions?editions=WOS.IC
  sourceTypes:
    Enrichment Source
    Index Database
DeliveryMethod no_fulltext_linktorsrc
Discipline Chemistry
EISSN 1520-6041
EndPage 4494
ExternalDocumentID 000305588000014
GrantInformation_xml – fundername: Fonds der Chemischen Industrie (AG)
– fundername: Deutsche Forschungsgemeinschaft (DFG); German Research Foundation (DFG)
  grantid: WA 2513/2-1
– fundername: German Academic Exchange Service; Deutscher Akademischer Austausch Dienst (DAAD)
GroupedDBID -DZ
-~X
123
17B
1KM
4.4
55A
5VS
6P2
7~N
AABXI
ABBLG
ABJNI
ABLBI
ABMVS
ABQRX
ABUCX
ABUFD
ACGFO
ACGFS
ACJ
ACNCT
ACS
ADHLV
AEESW
AENEX
AFEFF
AFFNX
AGXLV
AHGAQ
ALMA_UNASSIGNED_HOLDINGS
AQSVZ
BAANH
BLEPL
CS3
CUPRZ
D0L
DTL
DU5
EBS
ED~
EJD
F5P
GGK
GNL
GROUPED_WOS_SCIENCE_CITATION_INDEX_EXPANDED
GROUPED_WOS_WEB_OF_SCIENCE
IH9
IHE
JG~
LG6
P2P
ROL
TN5
TWZ
UI2
VF5
VG9
W1F
XKZ
XSW
YNT
YZZ
ID FETCH-LOGICAL-a285t-20ee3ce6cbdc3d3ba98a618a2abf4b47bddc93b992ed72a592f50820a813e4492
ISICitedReferencesCount 17
ISICitedReferencesURI https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=CitingArticles&UT=000305588000014
ISSN 0276-7333
IngestDate Tue Oct 28 00:36:52 EDT 2025
Fri Dec 05 22:55:59 EST 2025
IsPeerReviewed true
IsScholarly true
Issue 12
Keywords PENTADIENYL COMPLEXES
SANDWICH COMPLEXES
RING-SLIPPAGE
TRANSITION-METAL-COMPLEXES
HAPTOTROPIC SHIFTS
ORGANOMETALLIC COMPLEXES
PHOSPHINE CHEMISTRY
SUBSTITUTION-REACTIONS
HALF-OPEN METALLOCENES
ELECTRONIC-STRUCTURE
Language English
LinkModel OpenURL
LogoURL https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg
MergedId FETCHMERGED-LOGICAL-a285t-20ee3ce6cbdc3d3ba98a618a2abf4b47bddc93b992ed72a592f50820a813e4492
ORCID 0000-0002-6709-3673
0000-0002-5364-0357
0000-0002-4682-8749
PageCount 15
ParticipantIDs webofscience_primary_000305588000014CitationCount
webofscience_primary_000305588000014
PublicationCentury 2000
PublicationDate 2012-06-25
PublicationDateYYYYMMDD 2012-06-25
PublicationDate_xml – month: 06
  year: 2012
  text: 2012-06-25
  day: 25
PublicationDecade 2010
PublicationPlace WASHINGTON
PublicationPlace_xml – name: WASHINGTON
PublicationTitle Organometallics
PublicationTitleAbbrev ORGANOMETALLICS
PublicationYear 2012
Publisher Amer Chemical Soc
Publisher_xml – name: Amer Chemical Soc
References Rajapakshe, A (WOS:000236700400012) 2006; 25
WILSON, DR (WOS:A1980KE71000047) 1980; 102
PACIELLO, RA (WOS:A1990CH54200038) 1990; 9
Veiros, LF (WOS:000166165800004) 2000; 19
Weismann, D (WOS:000290211900002) 2011; 17
REREK, ME (WOS:A1984TL65600026) 1984; 106
Basta, R (WOS:000172577800025) 2001; 637
Ornelas, C (WOS:000262521800048) 2009; 131
Tobisch, S (WOS:000185957300022) 2003; 683
Hartwig, J. F. (000305588000014.59) 2010
BUNEL, EE (WOS:A1985AQT6400034) 1985; 4
Calhorda, MJ (WOS:000080701200003) 1999; 185-6
Gamero-Melo, P (WOS:000298897700022) 2012; 31
RITTINGER, S (WOS:A1992HP32100012) 1992; 11
HARTDAVI.AJ (WOS:A1969E463900019) 1969
Ogasawara, M (WOS:000178778100038) 2002; 21
Walter, M.D. (000305588000014.125) 2006
Frisch, M.J. (000305588000014.45) 2009
DOLG, M (WOS:A1993LE95100012) 1993; 97
Walter, MD (WOS:000294263700011) 2011; 35
Bi, SW (WOS:000226924800029) 2005; 24
Herbert, DE (WOS:000254173600082) 2008; 130
ERNST, RD (WOS:A1985ACP4100005) 1985; 18
Tamm, M (WOS:000243577000040) 2007; 26
Peruzzini, M (WOS:000225673500032) 2004; 689
FernandezGalan, R (WOS:A1997XR55900006) 1997; 16
Bleeke, JR (WOS:000283572100049) 2010; 29
GLEITER, R (WOS:A1989T290000006) 1989; 8
OCONNOR, JM (WOS:A1987G968000002) 1987; 87
Zhao, Y (WOS:000253323800001) 2008; 41
DIMAURO, PT (WOS:A1987K043800020) 1987; 6
Hart-Davis, A.J. (000305588000014.58) 1970; 4
Ariafard, A (WOS:000228945500001) 2005; 24
Bleeke, JR (WOS:000301895900012) 2012; 31
Honzícek, J (WOS:000287546600010) 2011; 30
Silva, LC (WOS:000239887600021) 2006; 25
Elschenbroich, C. (000305588000014.36) 1985; 4
JONAS, K (WOS:A1990DG15200039) 1990; 62
Mandal, SK (WOS:000181342800038) 2003
BLEEKE, JR (WOS:A1991FB88100010) 1991; 405
Wallasch, MW (WOS:000274530400015) 2010; 29
Maekawa, M. (000305588000014.86) 1000
REREK, ME (WOS:A1983RQ18900017) 1983
Wallasch, M (WOS:000228871800029) 2005; 44
JONAS, K (WOS:A1995QM56100013) 1995; 50
Tamm, M (WOS:000187810300054) 2003; 629
Ernst, RD (WOS:000085441900004) 1999; 21
FREEMAN, JW (WOS:A1991GB29800023) 1991; 113
Walter, MD (WOS:000257448500016) 2008; 27
Veiros, LF (WOS:000088605400026) 2000; 19
Walter, MD (WOS:000295732200007) 2011; 2
Son, SU (WOS:000083033500026) 1999; 18
Baker, RJ (WOS:000243018300013) 2006; 359
Steinborn, D. (000305588000014.112) 2007
Gemel, C (WOS:A1996TR68300010) 1996; 15
Walter, MD (WOS:000264932700008) 2009; 28
Labande, A (WOS:000173982500045) 2002; 124
BREUTEL, C (WOS:A1994NJ94600048) 1994; 116
Calhorda, MJ (WOS:000174100000013) 2002; 8
Layfield, RA (WOS:000295004300028) 2011; 47
SCHUMANN, H (WOS:A1986D314000003) 1986; 5
Chong, D (WOS:000252868800021) 2008; 27
(000305588000014.2) 2010
(WOS:000305588000014.1) 1996; 1
Ylijoki, KEO (WOS:000272560700028) 2009; 28
Witherell, RD (WOS:000253173300030) 2008; 130
Paz-Sandoval, MA (WOS:000238303400008) 2006; 250
KIRSS, RU (WOS:A1993MC32200058) 1993; 12
TRAKARNPRUK, W (WOS:A1995QB29400004) 1995; 485
BALZER, H (WOS:A1992HM76100028) 1992; 125
HSU, LY (WOS:A1989R739000032) 1989; 8
VANRAAIJ, EU (WOS:A1989CG32900023) 1989; 577
Vrieze, K. (000305588000014.122) 1975
BUSCHEL S 2009; 0694
Herberich, GE (WOS:A1996VV37400025) 1996; 15
Curnow, OJ (WOS:000229951600020) 2005; 690
Guzei, IA (WOS:000234772000039) 2006; 359
Brady, ED (WOS:000177358600053) 2002; 124
KOLLE, U (WOS:A1985AMM7400008) 1985; 290
Solomon, SA (WOS:000290628000068) 2011; 47
WILSON, DR (WOS:A1983RG72400025) 1983; 2
Díez-González, S (WOS:000244893500013) 2007; 251
BLAHA, JP (WOS:A1985AGH5200023) 1985; 107
Solin, N (WOS:000172602700028) 2001; 20
Filipuzzi, S (WOS:000252868800022) 2008; 27
LEE, GH (WOS:A1989AQ32300023) 1989; 8
Veiros, LF (WOS:000296024000011) 2011; 40
WORLEY, SD (WOS:A1982NZ18000023) 1982; 1
Cao, XY (WOS:000171719200003) 2001; 115
(000305588000014.3) 1987
WESTCOTT, SA (WOS:A1990EA49100051) 1990; 394
Fürstner, A (WOS:000257358300043) 2008; 130
Weng, WQ (WOS:000076217400018) 1998; 17
KOHL, FX (WOS:A1983QB91400015) 1983; 243
Cadierno, V (WOS:000083540400006) 1999; 193-5
Spencer, DM (WOS:000181342600026) 2003
MASUDA, K (WOS:A1994NV19800033) 1994; 473
Weychardt, H (WOS:000254565900017) 2008; 27
SKINNER, HA (WOS:A1985TX16100007) 1985; 57
BROOKHART, M (WOS:A1989R997300025) 1989; 111
GIBSON, DH (WOS:A1981LF47000011) 1981; 208
Glöckner, A (WOS:000270789200006) 2009; 28
LeSuer, R (WOS:000181902400022) 2003; 22
Navarro-Clemente, M.E. (000305588000014.90) 2002; 21
BLEEKE, JR (WOS:A1988N937000030) 1988; 7
Walter, MD (WOS:000262913600007) 2009; 28
Sheldrick, GM (WOS:000347804100002) 2015; 71
Jones, SC (WOS:000230761400017) 2005; 11
BROOKHART, M (WOS:A1989R997300026) 1989; 111
FISH, RW (WOS:A1976BD47500012) 1976; 105
Glöckner, A (WOS:000302186600058) 2012; 51
JI, LN (WOS:A1984SS82200016) 1984; 3
Bleeke, JR (WOS:000232745700002) 2005; 24
Heigl, OM (WOS:000078970000013) 1999; 574
TRAKARNPRUK, W (WOS:A1992HP32100045) 1992; 11
Effertz, U (WOS:000180408900008) 2003; 22
ERNST, RD (WOS:A1984TK93500001) 1984; 57
Malessa, M (WOS:000235745900022) 2006
Buchgraber, P (WOS:000186650800041) 2003; 22
SIMOES, JAM (WOS:A1990DK53200004) 1990; 90
HUTTNER, G (WOS:A1978EL02500008) 1978; 145
Zheng, XL (WOS:000169858900021) 2001; 20
Stahl, L (WOS:000250717000003) 2008; 55
CHENG, MH (WOS:A1989AP22600014) 1989; 373
LEE, GH (WOS:A1987K892000011) 1987; 6
Herberich, GE (WOS:000077727800046) 1998; 17
KUNDIG, EP (WOS:A1995TC46700026) 1995; 34
BOHM, MC (WOS:A1982NQ06600004) 1982; 104
LUSH, SF (WOS:A1986E021400027) 1986; 5
BOSCH, HW (WOS:A1992HY67400025) 1992; 11
Glöckner, A (WOS:000304082800006) 2012; 41
Ingleson, MJ (WOS:000301494100001) 2012; 48
JOB, R (WOS:A1979GT10800004) 1979; 15
CATHELINE, D (WOS:A1984TB91500022) 1984; 3
ERNST, RD (WOS:A1988R052900014) 1988; 88
Glöckner, Andreas (MEDLINE:21952146) 2011; 40
Kulsomphob, V (WOS:000089170200008) 2000
Herrmann, WA (WOS:A1997YF31800002) 1997; 36
Glöckner, A (WOS:000284872800005) 2010; 364
Guerrero, A (WOS:000189002500015) 2004
SHEN, JK (WOS:A1992JT75400017) 1992; 11
References_xml – volume: 113
  start-page: 6509
  year: 1991
  ident: WOS:A1991GB29800023
  article-title: SYNTHESES, CHARACTERIZATION, AND STRUCTURAL AND KINETIC-STUDIES OF HALF-OPEN CHROMOCENES AND THEIR LIGAND ADDUCTS
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 485
  start-page: 25
  year: 1995
  ident: WOS:A1995QB29400004
  article-title: SYNTHESIS AND CHARACTERIZATION OF FE(1-ME(3)SI-3-CH3C5H5)(2), AN OPEN FERROCENE DERIVED FROM AN UNSYMMETRIC PENTADIENYL LIGAND
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
– volume: 405
  start-page: 121
  year: 1991
  ident: WOS:A1991FB88100010
  article-title: PENTADIENYL-METAL-PHOSPHINE CHEMISTRY .21. SYNTHESIS AND CHARACTERIZATION OF ELECTRON-RICH (PENTADIENYL)IRON[1,2-BIS(DIETHYLPHOSPHINO)ETHANE] COMPLEXES
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
– volume: 193-5
  start-page: 147
  year: 1999
  ident: WOS:000083540400006
  article-title: Indenyl complexes of Group 8 metals
  publication-title: COORDINATION CHEMISTRY REVIEWS
– volume: 373
  start-page: 119
  year: 1989
  ident: WOS:A1989AP22600014
  article-title: SYNTHESIS, CHARACTERIZATION AND STRUCTURE OF (METHYL 2-BUTENOATE)IRON COMPLEXES
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
– volume: 5
  start-page: 1908
  year: 1986
  ident: WOS:A1986E021400027
  article-title: SYNTHESIS OF (C5H5)FE(CO)2(ETA-1-C5H7), (C5H5)FE(CO)(ETA-3-C5H7), AND (C5H5)FE(ETA-5-C5H7) INVOLVING THE ETA-1 -] SYN-ETA-3 -] ETA-5 ROUTE
  publication-title: ORGANOMETALLICS
– volume: 243
  start-page: 119
  year: 1983
  ident: WOS:A1983QB91400015
  article-title: AN IMPROVED SYNTHESIS OF 1,2,3,4,5-PENTAMETHYLCYCLOPENTADIENE
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
– volume: 102
  start-page: 5928
  year: 1980
  ident: WOS:A1980KE71000047
  article-title: BIS(PENTADIENYL)IRON COMPOUNDS - THE OPEN FERROCENES
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 18
  start-page: 56
  year: 1985
  ident: WOS:A1985ACP4100005
  article-title: METAL PENTADIENYL CHEMISTRY
  publication-title: ACCOUNTS OF CHEMICAL RESEARCH
– volume: 21
  start-page: 285
  year: 1999
  ident: WOS:000085441900004
  article-title: Pentadienyl ligands: Their properties, potential, and contributions to inorganic and organometallic chemistry
  publication-title: COMMENTS ON INORGANIC CHEMISTRY
– volume: 28
  start-page: 6807
  year: 2009
  ident: WOS:000272560700028
  article-title: Synthesis, Structure, and Reactivity of Alkyl-Substituted Half-Sandwich η5-Pentadienyl Complexes of Cobalt
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om900754h
– volume: 577
  start-page: 217
  year: 1989
  ident: WOS:A1989CG32900023
  article-title: MONOCARBONYL AND DICARBONYL COMPLEXES OF DECAMETHYLCHROMOCENE - A CO-INDUCED ETA5-]ETA3 RING-DISPLACEMENT
  publication-title: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
– volume: 41
  start-page: 157
  year: 2008
  ident: WOS:000253323800001
  article-title: Density functionals with broad applicability in chemistry
  publication-title: ACCOUNTS OF CHEMICAL RESEARCH
  doi: 10.1021/ar700111a
– volume: 3
  start-page: 1094
  year: 1984
  ident: WOS:A1984TB91500022
  article-title: PIANO-STOOL (PENTAMETHYLCYCLOPENTADIENYL)IRON COMPLEXES - SYNTHESES AND SIMPLE COORDINATION CHEMISTRY
  publication-title: ORGANOMETALLICS
– volume: 30
  start-page: 717
  year: 2011
  ident: WOS:000287546600010
  article-title: Reaction of Spiro[2.4]hepta-4,6-diene with Molybdenum(II) Indenyl Compounds: Effects of Substitution in the Indenyl Ligand
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om100840r
– volume: 87
  start-page: 307
  year: 1987
  ident: WOS:A1987G968000002
  article-title: RING-SLIPPAGE CHEMISTRY OF TRANSITION-METAL CYCLOPENTADIENYL AND INDENYL COMPLEXES
  publication-title: CHEMICAL REVIEWS
– start-page: 2403
  year: 1969
  ident: WOS:A1969E463900019
  article-title: REACTIONS OF PI-INDENYL COMPLEXES OF TRANSITION METALS .1. KINETICS AND MECHANISMS OF REACTIONS OF TRICARBONYL-PI-INDENYLMETHYLMOLYBDENUM WITH PHOSPHORUS(III) LIGANDS
  publication-title: JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL
– volume: 1
  start-page: 1
  year: 1996
  ident: WOS:000305588000014.1
  publication-title: STEREOLOGY IMAGE ANA
– volume: 57
  start-page: 1
  year: 1984
  ident: WOS:A1984TK93500001
  article-title: STRUCTURE AND BONDING IN METAL-PENTADIENYL AND RELATED-COMPOUNDS
  publication-title: STRUCTURE AND BONDING
– year: 2009
  ident: 000305588000014.45
  publication-title: Gaussian 09
– volume: 19
  start-page: 3127
  year: 2000
  ident: WOS:000088605400026
  article-title: The role of haptotropic shifts in phosphine addition to tricarbonylmanganese organometallic complexes: The indenyl effect revisited
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om000195j
– volume: 55
  start-page: 137
  year: 2008
  ident: WOS:000250717000003
  article-title: Pentadienyl complexes of the group 4 transition metals
  publication-title: ADVANCES IN ORGANOMETALLIC CHEMISTRY VOL 55
  doi: 10.1016/SO065-3055(07)55003-3
– volume: 27
  start-page: 430
  year: 2008
  ident: WOS:000252868800021
  article-title: Synthetic, structural, and electrochemical studies of edge-bridged open ferrocenes
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om700886k
– volume: 131
  start-page: 590
  year: 2009
  ident: WOS:000262521800048
  article-title: Giant Dendritic Molecular Electrochrome Batteries with Ferrocenyl and Pentamethylferrocenyl Termini
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja8062343
– volume: 359
  start-page: 701
  year: 2006
  ident: WOS:000234772000039
  article-title: Crystallographic and theoretical studies of (η5-C5Me5)Ru(2,4-dimethyl-η5-pentadienyl) and [(η5-C5Me5)Rh(2,4-dimethyl-η5-pentadienyl)][BF4]
  publication-title: INORGANICA CHIMICA ACTA
  doi: 10.1016/j.ica.2005.09.007
– start-page: 1016
  year: 2003
  ident: WOS:000181342800038
  article-title: Palladium(II) allyl complexes of chiral diphosphazane ligands: ambident coordination behaviour and stereodynamic studies in solution
  publication-title: DALTON TRANSACTIONS
  doi: 10.1039/b207447h
– volume: 40
  start-page: 11511
  year: 2011
  ident: MEDLINE:21952146
  article-title: Facile η5-η3 hapticity interconversion in pentamethylcyclopentadienyl ruthenium(II) complexes containing a phenylmethallyl ("open indenyl") ligand.
  publication-title: Dalton transactions (Cambridge, England : 2003)
  doi: 10.1039/c1dt11436k
– volume: 15
  start-page: 81
  year: 1979
  ident: WOS:A1979GT10800004
  article-title: IRON(O) OXIDATION BY IODINE IN TETRAHYDROFURAN - FACILE SYNTHESIS OF ANHYDROUS IRON(II) IODIDE
  publication-title: INORGANIC & NUCLEAR CHEMISTRY LETTERS
– volume: 97
  start-page: 5852
  year: 1993
  ident: WOS:A1993LE95100012
  article-title: RELATIVISTIC AND CORRELATION-EFFECTS FOR ELEMENT 105 (HAHNIUM, HA) - A COMPARATIVE-STUDY OF M AND MO (M = NB, TA, HA) USING ENERGY-ADJUSTED ABINITIO PSEUDOPOTENTIALS
  publication-title: JOURNAL OF PHYSICAL CHEMISTRY
– volume: 629
  start-page: 2408
  year: 2003
  ident: WOS:000187810300054
  article-title: Bioorganometallic coordination compounds:: Synthesis und structures of transition metal complexes containing tropidinyl and tropidine Ligands
  publication-title: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
  doi: 10.1002/zaac.200300263
– volume: 359
  start-page: 4797
  year: 2006
  ident: WOS:000243018300013
  article-title: Adduct formation of [(η7-C7H7)Zr(η5-C5H5)] with phosphines and N-heterocyclic carbenes:: An experimental and theoretical study
  publication-title: INORGANICA CHIMICA ACTA
  doi: 10.1016/j.ica.2006.05.010
– volume: 9
  start-page: 260
  year: 1990
  ident: WOS:A1990CH54200038
  article-title: SYNTHESIS AND REACTIVITY OF HALIDE, HYDRIDE, AND ALKYL DERIVATIVES OF (PENTAMETHYLCYCLOPENTADIENYL)(BISPHOSPHINE)IRON(II)
  publication-title: ORGANOMETALLICS
– volume: 364
  start-page: 23
  year: 2010
  ident: WOS:000284872800005
  article-title: Coordination chemistry of half-open trozircenes: Adduct formation of [(η7-C7H7)Zr(η5-2,4-C7H11)] with isocyanides, phosphines and N-heterocyclic carbenes
  publication-title: INORGANICA CHIMICA ACTA
  doi: 10.1016/j.ica.2010.06.049
– volume: 25
  start-page: 4391
  year: 2006
  ident: WOS:000239887600021
  article-title: Synthesis, structure, and solution dynamics of neutral allylnickel complexes of N-heterocyclic carbenes
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om060444p
– volume: 21
  start-page: 592
  year: 2002
  ident: 000305588000014.90
  publication-title: Organometallics
– volume: 11
  start-page: 3215
  year: 1992
  ident: WOS:A1992JT75400017
  article-title: SYNTHESES, KINETICS, AND MECHANISM OF LIGAND SUBSTITUTION-REACTIONS OF 17-ELECTRON HALF-OPEN CHROMOCENE CARBONYL-COMPLEXES
  publication-title: ORGANOMETALLICS
– start-page: 638
  year: 2003
  ident: WOS:000181342600026
  article-title: Synthesis, structure and hapticity interconversion reactions of pentahapto-bonded cyclooctadienyl complexes of molybdenum
  publication-title: DALTON TRANSACTIONS
  doi: 10.1039/b209975f
– volume: 40
  start-page: 11138
  year: 2011
  ident: WOS:000296024000011
  article-title: Indenyl effect in dissociative reactions. Nucleophilic substitution in iron carbonyl complexes: a case study
  publication-title: DALTON TRANSACTIONS
  doi: 10.1039/c1dt00010a
– volume: 28
  start-page: 2005
  year: 2009
  ident: WOS:000264932700008
  article-title: Spin Equilibria in Monomeric Manganocenes: Solid-State Magnetic and EXAFS Studies
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om800922j
– volume: 62
  start-page: 1169
  year: 1990
  ident: WOS:A1990DG15200039
  article-title: NEW FINDINGS IN THE ARENE CHEMISTRY OF THE 3D TRANSITION-METALS
  publication-title: PURE AND APPLIED CHEMISTRY
– volume: 290
  start-page: 77
  year: 1985
  ident: WOS:A1985AMM7400008
  article-title: PENTAMETHYLCYCLOPENTADIENYL TRANSITION-METAL COMPLEXES .10. SEMISANDWICH COMPLEXES OF FE AND NI AS REACTIVE INTERMEDIATE PRODUCTS
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
– volume: 11
  start-page: 1454
  year: 1992
  ident: WOS:A1992HP32100012
  article-title: DECAMETHYLBIMETALLOCENES
  publication-title: ORGANOMETALLICS
– volume: 124
  start-page: 1782
  year: 2002
  ident: WOS:000173982500045
  article-title: Supramolecular gold nanoparticles for the redox recognition of oxoanions: Syntheses, titrations, stereoelectronic effects, and selectivity
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja017015x
– year: 2010
  ident: 000305588000014.59
  publication-title: Organotransition Metal Chemistry: From Bonding to Catalysis
– volume: 1
  start-page: 134
  year: 1982
  ident: WOS:A1982NZ18000023
  article-title: ELECTRONIC-STRUCTURE OF CONFORMATIONAL ISOMERS OF (ETA-3-ALLYL)RUTHENIUM COMPLEXES
  publication-title: ORGANOMETALLICS
– volume: 104
  start-page: 2699
  year: 1982
  ident: WOS:A1982NQ06600004
  article-title: ELECTRONIC-STRUCTURE OF ORGANO-METALLIC COMPOUNDS .18. ELECTRONIC-STRUCTURE OF BIS(PENTADIENYL)IRON - SEMI-EMPIRICAL CALCULATIONS AND PHOTO-ELECTRON SPECTRA
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 11
  start-page: 4473
  year: 2005
  ident: WOS:000230761400017
  article-title: Electronic coupling in mixed-valence dinuclear ferrocenes and cobaltocenes with saturated bridging groups
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  doi: 10.1002/chem.200500179
– volume: 34
  start-page: 2161
  year: 1995
  ident: WOS:A1995TC46700026
  article-title: ADDITIONS OF CARBANIONS TO A CATIONIC CYCLOPENTADIENYL(NAPHTHALENE)IRON COMPLEX
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH
– volume: 8
  start-page: 2248
  year: 1989
  ident: WOS:A1989AQ32300023
  article-title: PREPARATION AND PROPERTIES OF MOLYBDENUM PENTADIENYL COMPLEXES - A FACILE ETA-5-REVERSIBLE-ETA-3 REVERSIBLE INTERCONVERSION FOR A PENTADIENYL LIGAND
  publication-title: ORGANOMETALLICS
– volume: 11
  start-page: 2087
  year: 1992
  ident: WOS:A1992HY67400025
  article-title: GENERAL-ROUTE TO THE HALF-OPEN METALLOCENES C5ME5RU(PENTADIENYL) AND C5ME5RU(DIENE)CL - X-RAY STRUCTURES OF AN OPTICALLY-ACTIVE HALF-OPEN METALLOCENE AND OF A DIMETALLIC RUTHENABENZENE COMPLEX
  publication-title: ORGANOMETALLICS
– volume: 27
  start-page: 437
  year: 2008
  ident: WOS:000252868800022
  article-title: Structure, bonding, and dynamics of several palladium η3-allyl carbene complexes
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om7010613
– volume: 683
  start-page: 181
  year: 2003
  ident: WOS:000185957300022
  article-title: Theoretical exploration of structure-reactivity relationships in organometallic chemistry:: butadiene insertion into the organyl-transition-metal bond and conversion of the allyl-transition-metal fragment in the [NiII(η5-Cp)(η1-phenyl)(η2-butadiene)] complex
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  doi: 10.1016/S0022-328X(03)00596-5
– start-page: 1208
  year: 1983
  ident: WOS:A1983RQ18900017
  article-title: THE INDENYL LIGAND EFFECT ON THE RATE OF SUBSTITUTION-REACTIONS OF RH(ETA-C9H7)(CO)2 AND MN(ETA-C9H7)(CO)3
  publication-title: JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
– volume: 130
  start-page: 4166
  year: 2008
  ident: WOS:000254173600082
  article-title: Strain-controlled, photochemically, or thermally promoted haptotropic shifts of cyclopentadienyl Ligands in group 8 metallocenophanes
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja077334+
– volume: 31
  start-page: 170
  year: 2012
  ident: WOS:000298897700022
  article-title: Chemistry of Iridium(I) Cyclooctadiene Compounds with Thiapentadienyl, Sulfinylpentadienyl, and Butadienesulfonyl Ligands
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om2007166
– volume: 4
  start-page: 1680
  year: 1985
  ident: WOS:A1985AQT6400034
  article-title: PENTAMETHYLCYCLOPENTADIENYL ACETYLACETONATE COMPLEXES OF IRON(II), COBALT(II), AND NICKEL(II) - CONVENIENT SYNTHETIC ENTRIES TO MONO-ETA-5-C5ME5 DERIVATIVES
  publication-title: ORGANOMETALLICS
– volume: 574
  start-page: 94
  year: 1999
  ident: WOS:000078970000013
  article-title: 1,1-bis(1",2",3",4",5"-pentamethylferrocen-1′-yl)ethene
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
– volume: 22
  start-page: 1487
  year: 2003
  ident: WOS:000181902400022
  article-title: Structural, spectroscopic, and electrochemical studies of edge-bridged open ferrocenes
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om020779g
– year: 2007
  ident: 000305588000014.112
  publication-title: Grundlagen der Metallorganischen Komplexkatalyse
– start-page: 3086
  year: 2000
  ident: WOS:000089170200008
  article-title: Incorporation of phenyl-substituted pentadienyl ligands in (pentamethylcyclopentadienyl)ruthenium complexes
  publication-title: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
– volume: 6
  start-page: 1947
  year: 1987
  ident: WOS:A1987K043800020
  article-title: NEW SANDWICH COMPLEXES CONTAINING 6,6-DIMETHYLCYCLOHEXADIENYL (DMCH) (DMCH)2M (M = TI, V, CR, FE) AND (DMCH)2M-CO (M = TI, V)
  publication-title: ORGANOMETALLICS
– volume: 111
  start-page: 567
  year: 1989
  ident: WOS:A1989R997300026
  article-title: SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION, DYNAMICS, AND PHOSPHINE TRAPPING OF CP(CO)FE[ETA-3-CH(R)C6H5] COMPLEXES (R = H, OCH3)
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 125
  start-page: 733
  year: 1992
  ident: WOS:A1992HM76100028
  article-title: STRUCTURAL NMR INVESTIGATIONS ON ALLYLLITHIUM COMPOUNDS
  publication-title: CHEMISCHE BERICHTE-RECUEIL
– volume: 19
  start-page: 5549
  year: 2000
  ident: WOS:000166165800004
  article-title: Haptotropic shifts in cyclopentadienyl organometallic complexes: Ring folding vs ring slippage
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om000589a
– volume: 15
  start-page: 5236
  year: 1996
  ident: WOS:A1996VV37400025
  article-title: Triple-decker complexes .12. Triple-decker complexes with bridging boratabenzene ligands. Syntheses, structures of [(mu-C(5)H(5)BMe)(FeCp*)(2)]PF6 and of [(mu-C(5)H(5)BMe){Rh(COD)}(2)]CF3SO3, and boratabenzene transfer reactions
  publication-title: ORGANOMETALLICS
– volume: 637
  start-page: 172
  year: 2001
  ident: WOS:000172577800025
  article-title: Bonding in 'closed,' open, and half-open ferrocenes: new insight from structural and Mossbauer spectroscopic studies
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
– year: 1000
  ident: 000305588000014.86
  publication-title: UNPUB
– volume: 71
  start-page: 3
  year: 2015
  ident: WOS:000347804100002
  article-title: Crystal structure refinement with SHELXL
  publication-title: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
  doi: 10.1107/S2053229614024218
– volume: 24
  start-page: 680
  year: 2005
  ident: WOS:000226924800029
  article-title: Isomerism of Cp-containing transition metal allyl complexes
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om049256u
– volume: 35
  start-page: 1842
  year: 2011
  ident: WOS:000294263700011
  article-title: [Cp′FeI]2 as convenient entry into iron-modified pincer complexes: bimetallic η6,κ1-POCOP-pincer iron iridium compounds
  publication-title: NEW JOURNAL OF CHEMISTRY
  doi: 10.1039/c1nj20399a
– volume: 24
  start-page: 2241
  year: 2005
  ident: WOS:000228945500001
  article-title: Mechanism of endo-exo interconversion in η3-allyl Cp complexes:: A longstanding unresolved issue
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om050161h
– volume: 251
  start-page: 874
  year: 2007
  ident: WOS:000244893500013
  article-title: Stereoelectronic parameters associated with N-heterocyclic carbene (NHC) ligands:: A quest for understanding
  publication-title: COORDINATION CHEMISTRY REVIEWS
  doi: 10.1016/j.ccr.2006.10.004
– volume: 22
  start-page: 264
  year: 2003
  ident: WOS:000180408900008
  article-title: Reaction of pentadienyl complexes with metal carbonyls:: Synthetic, structural, and theoretical studies of metallabenzene π-complexes
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om020789h
– volume: 4
  start-page: 442
  year: 1970
  ident: 000305588000014.58
  publication-title: Inorg. Chim. Acta
– volume: 26
  start-page: 761
  year: 2007
  ident: WOS:000243577000040
  article-title: Efficient direct synthesis of tropidinyl titanium and zirconium complexes by allylic CH-activation of 8-methyl-8-azabicyclo[3.2.1]oct-2-ene (tropidine)
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om0609564
– volume: 29
  start-page: 806
  year: 2010
  ident: WOS:000274530400015
  article-title: Reactive Sigma-Aryliron Complexes or Iron-Promoted Coupling of Two Phenyl Anions to One Bis(cyclohexadienylidene) Ligand: Synthesis, Structure, Mass Spectrometry, and DFT Calculations
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om900870j
– volume: 2
  start-page: 2120
  year: 2011
  ident: WOS:000295732200007
  article-title: Reactivity studies on [Cp′FeI]2: From iron hydrides to P4-activation
  publication-title: CHEMICAL SCIENCE
  doi: 10.1039/c1sc00413a
– volume: 145
  start-page: 329
  year: 1978
  ident: WOS:A1978EL02500008
  article-title: STRUCTURE OF (C5H5)2W(CO)2, A COMPOUND CONTAINING A BENT TRIHAPTO-CYCLOPENTADIENYL LIGAND
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
– volume: 16
  start-page: 3758
  year: 1997
  ident: WOS:A1997XR55900006
  article-title: New chiral palladium(0) and -(II) complexes of (aminoferrocenyl)phosphine ligands PPFA and PTFA. X-ray crystal structure analysis and fluxional behavior involving alkene rotation, Pd-N bond rupture, and selective eta(3)-eta(1)-eta(3) allyl isomerization
  publication-title: ORGANOMETALLICS
– volume: 4
  start-page: 2068
  year: 1985
  ident: 000305588000014.36
  publication-title: Organometallics
– volume: 7
  start-page: 1417
  year: 1988
  ident: WOS:A1988N937000030
  article-title: PENTADIENYL-METAL-PHOSPHINE CHEMISTRY .15. SYNTHESIS, STRUCTURE, AND REACTIVITY OF (ETA-5-PENTADIENYL)(ETA-3-PENTADIENYL)FE(PR3) COMPLEXES
  publication-title: ORGANOMETALLICS
– volume: 124
  start-page: 9556
  year: 2002
  ident: WOS:000177358600053
  article-title: Spin-state alteration from sterically enforced ligand rotation in bis(indenyl)chromium(II) complexes
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja012390a
– start-page: 857
  year: 2006
  ident: WOS:000235745900022
  article-title: Polar cofacially fixed sandwich complexes: Do they demonstrate second harmonic generation (SHG)?
  publication-title: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
  doi: 10.1002/ejic.200500812
– volume: 47
  start-page: 10623
  year: 2011
  ident: WOS:000295004300028
  article-title: Structure and bonding in three-coordinate N-heterocyclic carbene adducts of iron(II) bis(trimethylsilyl) amide
  publication-title: CHEMICAL COMMUNICATIONS
  doi: 10.1039/c1cc14576b
– volume: 130
  start-page: 8773
  year: 2008
  ident: WOS:000257358300043
  article-title: Preparation, structure, and reactivity of nonstabilized organoiron compounds.: Implications for iron-catalyzed cross coupling reactions
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja801466t
– volume: 31
  start-page: 2219
  year: 2012
  ident: WOS:000301895900012
  article-title: Synthesis, Structure, Spectroscopy, and Reactivity of Azapentadienyl-Cobalt-Phosphine Complexes
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om2011326
– volume: 107
  start-page: 2694
  year: 1985
  ident: WOS:A1985AGH5200023
  article-title: RELATIVE IMPORTANCE OF DISSOCIATIVE LOSS OF CARBON-MONOXIDE AND FORMATION OF BENZYL RADICALS FROM PHOTOEXCITATION OF (ETA-5-C5R5)FE(CO)2(ETA-1-CH2C6H5) AND EVIDENCE FOR REACTION OF CARBON-MONOXIDE WITH 17-ELECTRON RADICALS
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 6
  start-page: 2094
  year: 1987
  ident: WOS:A1987K892000011
  article-title: SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF IRON DIENYL COMPLEXES
  publication-title: ORGANOMETALLICS
– volume: 21
  start-page: 4853
  year: 2002
  ident: WOS:000178778100038
  article-title: Effects of bidentate phosphine Ligands on syn-anti isomerization in π-allylpalladium complexes
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om020680+
– volume: 689
  start-page: 4319
  year: 2004
  ident: WOS:000225673500032
  article-title: Functionalization of white phosphorus in the coordination sphere of transition metal complexes
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  doi: 10.1016/j.jorganchem.2004.05.041
– volume: 18
  start-page: 4114
  year: 1999
  ident: WOS:000083033500026
  article-title: Chemistry of [(1H-hydronaphthalene)Mn(CO)3]:: The role of ring-slippage in substitution, catalytic hydrosilylation, and molecular crystal structure of [(η3-C10H9)Mn(CO)3P(OMe)3]
  publication-title: ORGANOMETALLICS
– volume: 105
  start-page: 101
  year: 1976
  ident: WOS:A1976BD47500012
  article-title: THERMAL AND PHOTOCHEMICAL INTERCONVERSIONS OF ISOMERIC MONOCARBONYL ETA5-CYCLOPENTADIENYL(ETA3-ALLYL)IRON COMPLEXES
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
– volume: 28
  start-page: 698
  year: 2009
  ident: WOS:000262913600007
  article-title: Cerocene Revisited: The Electronic Structure of and Interconversion Between Ce2(C8H8)3 and Ce(C8H8)2
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om7012327
– volume: 8
  start-page: 298
  year: 1989
  ident: WOS:A1989T290000006
  article-title: HALF-OPEN METALLOCENES OF IRON, RUTHENIUM, AND OSMIUM - SYNTHESIS, CHARACTERIZATION, PHOTOELECTRON-SPECTROSCOPY, AND THEORETICAL CALCULATIONS
  publication-title: ORGANOMETALLICS
– volume: 111
  start-page: 559
  year: 1989
  ident: WOS:A1989R997300025
  article-title: FORMATION OF CP(CO)(PR3)FECH(OCH3)C6H5 COMPLEXES VIA PR3 SUBSTITUTION-REACTIONS, HYDRIDE ADDITION TO CP(CO)(PR3)FE=C(OCH3)C6H5+, AND METHOXIDE ADDITION TO CP(CO)(PR3)FE=CHC6H5+ - KINETIC AND THERMODYNAMIC DIASTEREOSELECTIVITIES - RELATIVE REACTIVITIES OF SYNCLINAL AND ANTICLINAL IRON CARBENE ISOMERS
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 473
  start-page: 285
  year: 1994
  ident: WOS:A1994NV19800033
  article-title: INTERCONVERSION BETWEEN (C5R5)RU(IV)(ALLYL) AND (C5R5)RU(II)(DIENE) COMPLEXES
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
– volume: 0694
  start-page: 01244
  year: 2009
  publication-title: J ORGANOMET CHEM
  doi: 10.1016/J.JORGANCHEM.2009.01.055
– year: 1975
  ident: 000305588000014.122
  article-title: Fluxional Allyl Complexes
  publication-title: Dynamic Nuclear Magnetic Resonance Spectroscopy
– volume: 22
  start-page: 5144
  year: 2003
  ident: WOS:000186650800041
  article-title: Syntheses, properties, and X-ray crystal structures of piano-stool iron complexes bearing an N-heterocyclic carbene ligand
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om034056o
– volume: 88
  start-page: 1255
  year: 1988
  ident: WOS:A1988R052900014
  article-title: STRUCTURAL AND REACTIVITY PATTERNS IN TRANSITION-METAL PENTADIENYL CHEMISTRY
  publication-title: CHEMICAL REVIEWS
– volume: 24
  start-page: 5190
  year: 2005
  ident: WOS:000232745700002
  article-title: Synthesis and reactivity of heteropentadienyl-transition-metal complexes
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om058044+
– volume: 25
  start-page: 1914
  year: 2006
  ident: WOS:000236700400012
  article-title: Heteropentadienyl analogues of half-open ruthenocenes: Metal-ligand interactions and electronic structure perturbations
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om060100z
– volume: 15
  start-page: 532
  year: 1996
  ident: WOS:A1996TR68300010
  article-title: Synthesis and characterization of dibromo-containing ruthenium(IV) eta(3)-allyl and ruthenium(IV) eta(4)-diene complexes. Formation of [Ru(eta(5)-C(5)Me(5))Br-3](-) and [Ru(eta(5)-C(5)Me(5))Br-3](2)
  publication-title: ORGANOMETALLICS
– volume: 17
  start-page: 4700
  year: 2011
  ident: WOS:000290211900002
  article-title: High-Spin Cyclopentadienyl Complexes: A Single-Molecule Magnet Based on the Aryl-Iron(II) Cyclopentadienyl Type
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  doi: 10.1002/chem.201003288
– volume: 8
  start-page: 241
  year: 1989
  ident: WOS:A1989R739000032
  article-title: A COMPARISON OF THE STRUCTURES OF EXO-(ETA-5-CYCLOPENTADIENYL) AND ENDO-(ETA-5-CYCLOPENTADIENYL)(ETA-3-2-METHYLALLYL)RUTHENIUM CARBONYL
  publication-title: ORGANOMETALLICS
– volume: 47
  start-page: 6162
  year: 2011
  ident: WOS:000290628000068
  article-title: A donor-functionalized, silyl-substituted pentadienyllithium: structural insight from experiment and theory
  publication-title: CHEMICAL COMMUNICATIONS
  doi: 10.1039/c1cc11697e
– volume: 57
  start-page: 79
  year: 1985
  ident: WOS:A1985TX16100007
  article-title: METAL-LIGAND BOND-ENERGIES IN ORGANOMETALLIC COMPOUNDS
  publication-title: PURE AND APPLIED CHEMISTRY
– volume: 130
  start-page: 2176
  year: 2008
  ident: WOS:000253173300030
  article-title: Cobalt-mediated η5-pentadienyl/alkyne [5+2] cycloaddition.: Synthesis and characterization of unbridged η2,η3-coordinated cycloheptadienyl complexes
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja710568d
– volume: 185-6
  start-page: 37
  year: 1999
  ident: WOS:000080701200003
  article-title: Ring slippage in indenyl complexes: structure and bonding
  publication-title: COORDINATION CHEMISTRY REVIEWS
– volume: 50
  start-page: 394
  year: 1995
  ident: WOS:A1995QM56100013
  article-title: PENTAMETHYLCYCLOPENTADIENYLBIS(ETHENE)IRON - A 17E HALFSANDWICH COMPLEX WITH EASILY DISPLACEABLE ETHENE LIGANDS
  publication-title: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
– volume: 11
  start-page: 1686
  year: 1992
  ident: WOS:A1992HP32100045
  article-title: HALF-OPEN RUTHENOCENES DERIVED FROM [RU(C5ME5)CL]4 - SYNTHESES, CHARACTERIZATIONS, AND SOLID-STATE STRUCTURES
  publication-title: ORGANOMETALLICS
– volume: 106
  start-page: 5908
  year: 1984
  ident: WOS:A1984TL65600026
  article-title: KINETICS AND MECHANISM OF SUBSTITUTION-REACTIONS OF ETA-5-CYCLOPENTADIENYLDICARBONYLRHODIUM(I) DERIVATIVES - RATE ENHANCEMENT OF ASSOCIATIVE SUBSTITUTION IN CYCLOPENTADIENYLMETAL COMPOUNDS
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 48
  start-page: 3579
  year: 2012
  ident: WOS:000301494100001
  article-title: N-Heterocyclic carbene chemistry of iron: fundamentals and applications
  publication-title: CHEMICAL COMMUNICATIONS
  doi: 10.1039/c2cc18021a
– volume: 41
  start-page: 6614
  year: 2012
  ident: WOS:000304082800006
  article-title: How big is a Cp? Cycloheptatrienyl zirconium complexes with bulky cyclopentadienyl and indenyl ligands
  publication-title: DALTON TRANSACTIONS
  doi: 10.1039/c2dt12132h
– volume: 2
  start-page: 1220
  year: 1983
  ident: WOS:A1983RG72400025
  article-title: SYNTHESIS AND CHARACTERIZATION OF BIS(PENTADIENYL)IRON AND SEVERAL METHYLATED DERIVATIVES
  publication-title: ORGANOMETALLICS
– volume: 20
  start-page: 5464
  year: 2001
  ident: WOS:000172602700028
  article-title: Mechanism of the η3-η1-η3 isomerization in allylpalladium complexes:: Solvent coordination, ligand, and substituent effects
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om010793d
– volume: 116
  start-page: 4067
  year: 1994
  ident: WOS:A1994NJ94600048
  article-title: AN UNUSUAL, SELECTIVE ETA(3)-ETA(1) ALLYL ISOMERIZATION IN A CHIRAL ALLYLIC ALKYLATION CATALYST
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– start-page: 30
  year: 2006
  ident: 000305588000014.125
  publication-title: New J. Chem.
– volume: 20
  start-page: 3097
  year: 2001
  ident: WOS:000169858900021
  article-title: Lithium (S)-1-[2′-methoxymethyl)pyrrolidin-1′-y1] benzene.: An enantiopure lithium salt possessing a novel polymeric structure
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om010203b
– year: 1987
  ident: 000305588000014.3
  publication-title: Bruker AM Series User Manual
– volume: 12
  start-page: 4145
  year: 1993
  ident: WOS:A1993MC32200058
  article-title: SYNTHESIS OF UNSYMMETRICAL RUTHENOCENES BY GAS-PHASE ELECTROCYCLIC REACTIONS OF PENTADIENYLRUTHENIUM COMPLEXES
  publication-title: ORGANOMETALLICS
– volume: 29
  start-page: 5057
  year: 2010
  ident: WOS:000283572100049
  article-title: Synthesis, Structure, Spectroscopy, and Reactivity of Oxapentadienyl-Cobalt-Phosphine Complexes
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om100361a
– year: 2010
  ident: 000305588000014.2
  publication-title: DNMR module of TopSpin2.1p16
– volume: 27
  start-page: 1479
  year: 2008
  ident: WOS:000254565900017
  article-title: Acyclic diene metathesis polymerization of divinylarenes and divinylferrocenes with Grubbs-type olefin metathesis catalysts
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om701277p
– volume: 17
  start-page: 4240
  year: 1998
  ident: WOS:000076217400018
  article-title: Synthesis, characterization, and structural studies of transition metal open fulvalene complexes
  publication-title: ORGANOMETALLICS
– volume: 90
  start-page: 629
  year: 1990
  ident: WOS:A1990DK53200004
  article-title: TRANSITION-METAL HYDROGEN AND METAL-CARBON BOND STRENGTHS - THE KEYS TO CATALYSIS
  publication-title: CHEMICAL REVIEWS
– volume: 28
  start-page: 5866
  year: 2009
  ident: WOS:000270789200006
  article-title: Cycloheptatrienyl-Pentadienyl Complexes of Zirconium (Half-Open Trozircenes): Syntheses, Structures, Bonding, and Chemistry
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om900456s
– volume: 44
  start-page: 2597
  year: 2005
  ident: WOS:000228871800029
  article-title: Phenolate complexes of iron(II) in different spin states
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.200462153
– volume: 690
  start-page: 3018
  year: 2005
  ident: WOS:000229951600020
  article-title: Synthesis, structures and spectroelectrochemistry of methyl-substituted bis(η5-indenyl)iron(II) complexes
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  doi: 10.1016/j.jorganchem.2005.03.036
– volume: 36
  start-page: 2162
  year: 1997
  ident: WOS:A1997YF31800002
  article-title: N-heterocyclic carbenes
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
– volume: 27
  start-page: 2959
  year: 2008
  ident: WOS:000257448500016
  article-title: Preparation and reactions of base-free bis(1,3-di-tert-butylcyclopentadienyl)titanium, Cp′2 Ti, and related compounds
  publication-title: ORGANOMETALLICS
  doi: 10.1021/om7012315
– volume: 5
  start-page: 1296
  year: 1986
  ident: WOS:A1986D314000003
  article-title: ORGANOMETALLIC COMPOUNDS OF THE LANTHANIDES .36. BIS(PENTAMETHYLCYCLOPENTADIENYL) HALIDE AND ALKYL DERIVATIVES OF THE LANTHANIDES
  publication-title: ORGANOMETALLICS
– volume: 17
  start-page: 5931
  year: 1998
  ident: WOS:000077727800046
  article-title: Cyclopentadienyl(pentamethylcyclopentadienyl)iron derivatives. A new and highly selective synthesis
  publication-title: ORGANOMETALLICS
– start-page: 549
  year: 2004
  ident: WOS:000189002500015
  article-title: Apparent allyl rotation in new allylpalladium(II) complexes with pyrazolyl N-donor ligands
  publication-title: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
  doi: 10.1002/ejic.200300359
– volume: 115
  start-page: 7348
  year: 2001
  ident: WOS:000171719200003
  article-title: Valence basis sets for relativistic energy-consistent small-core lanthanide pseudopotentials
  publication-title: JOURNAL OF CHEMICAL PHYSICS
– volume: 3
  start-page: 740
  year: 1984
  ident: WOS:A1984SS82200016
  article-title: KINETICS AND MECHANISM OF SUBSTITUTION-REACTIONS OF MN(ETA-5-C9H7)(CO)3 AND MN(ETA-5-C13H9)(CO)3
  publication-title: ORGANOMETALLICS
– volume: 394
  start-page: 777
  year: 1990
  ident: WOS:A1990EA49100051
  article-title: FLEXIBLE COORDINATION OF INDENYL LIGANDS IN SANDWICH COMPLEXES OF TRANSITION-METALS - MOLECULAR-STRUCTURES OF [(ETA-C9R7)2M] (M = FE, R = H, ME, M = CO, NI, R = H) - DIRECT MEASUREMENT OF THE DEGREE OF SLIP-FOLD DISTORTION AS A FUNCTION OF D-ELECTRON COUNT
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
– volume: 51
  start-page: 4368
  year: 2012
  ident: WOS:000302186600058
  article-title: From a Cycloheptatrienylzirconium Allyl Complex to a Cycloheptatrienylzirconium Imidazolin-2-iminato "Pogo Stick" Complex with Imido-Type Reactivity
  publication-title: INORGANIC CHEMISTRY
  doi: 10.1021/ic300129z
– volume: 250
  start-page: 1071
  year: 2006
  ident: WOS:000238303400008
  article-title: Half-open metallocenes with heterodienyl ligands and related compounds
  publication-title: COORDINATION CHEMISTRY REVIEWS
  doi: 10.1016/j.ccr.2005.11.002
– volume: 8
  start-page: 868
  year: 2002
  ident: WOS:000174100000013
  article-title: The nature of the indenyl effect
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
– volume: 208
  start-page: 89
  year: 1981
  ident: WOS:A1981LF47000011
  article-title: CONFORMATIONAL ISOMERISM IN ETA-5-CYCLOPENTADIENYL-ETA-3-ALLYLRUTHENIUM CARBONYL-COMPLEXES
  publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY
SSID ssj0006732
Score 2.1362998
Snippet [FeI2(thf)(2)] was sequentially treated with Li(C5Me5) and the potassium salt of the phenylmethallyl ("open indenyl") ligand oIndme, leading to selective...
Source Web of Science
SourceID webofscience
SourceType Enrichment Source
Index Database
StartPage 4480
SubjectTerms Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
Title Flexibility of an Open Indenyl Ligand in Iron(II) Complexes
URI http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=FullRecord&UT=000305588000014
Volume 31
WOS 000305588000014
WOSCitedRecordID wos000305588000014
hasFullText
inHoldings 1
isFullTextHit
isPrint
link http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1Nb9QwELW2FAkuiBZQCwX50EPRKmXjJP5QT2hFSwRUSBTUW2XHTrVqNqmWpSp_hV_L-CPeqHBYDlyilXc3UTLPb2acN2OE9mtTpKqqSKKIpkkueJEIbVUWmTaMMcm4q3L99pGdnvLzc_F5NPrV18LcNKxt-e2tuP6vpoYxMLYtnf0Hc8eTwgB8BqPDEcwOx7UMf2xbXDrJq3t5DvPXikaACIBhfjaQhF_6hkvjcuF0IGVpVwYsL8Afg6IwRKuuULObGwjQm4Eq_qTpTHUVKmWcIlKuFtslEHcUjQ3kRxZ-atHNfTEQxJyzCEtb5t7Mfri91qc-XoVvxyeHwyUJq-2giS9fjlUA49jv4Es30HNCEkwTlvneF4cmcK7NYCe-_1VPysE1BPCRAcVCPjkZuOs895sk_-EKIHgBU3XzzPLYRKz8Xf-O_44bjOLEie-bBsTmEsgNtMGopfz0w6fo4ylzW9_F2-l7VpH0TbziX0MZF7acPUaPQr6B33qcbKGRabfRg2m_zd8TdDTAC-5qLFts8YIDXrDHC57BCODloCxf44iVp-jr8buz6fsk7KiRSMKLJcwTY7LK0ErpKtOZkoJLmnJJpKpzlTOldSUyJQQxmhFZCFIXNkaUPM0MPGnyDN1ru9bsIMxqaSDch-xXWN6nIq2pkAoS8FpzqvQu2h_e_cW1b55ycefp7qJ0nZ9NQ8N626hh-Xy9U79AD1fg3EObNUxw8xLdr26Ws--LV86gvwE-oXGi
linkProvider Clarivate
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Flexibility+of+an+Open+Indenyl+Ligand+in+Iron%28II%29+Complexes&rft.jtitle=Organometallics&rft.au=Gloeckner%2C+Andreas&rft.au=Bannenberg%2C+Thomas&rft.au=Ibrom%2C+Kerstin&rft.au=Daniliuc%2C+Constantin+G.&rft.date=2012-06-25&rft.pub=Amer+Chemical+Soc&rft.issn=0276-7333&rft.eissn=1520-6041&rft.volume=31&rft.issue=12&rft.spage=4480&rft.epage=4494&rft_id=info:doi/10.1021%2Fom3003009&rft.externalDBID=n%2Fa&rft.externalDocID=000305588000014
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0276-7333&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0276-7333&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0276-7333&client=summon