Real-Time Tracking of Photoinduced Metal-Metal Bond Formation in a d8d8 Di-Iridium Complex by Vibrational Coherence and Femtosecond Stimulated Raman Spectroscopy

We report real-time dynamics of photoinduced metal-metal bond formation acquired from ultrafast time-resolved stimulated emission and femtosecond stimulated Raman spectra (FSRS) of [Ir2(2,5-dimethyl-2,5-diisocyanohexane)4]2+ (Ir(TMB)) in the region of low-frequency vibrations. Interpretation was sup...

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Bibliographic Details
Published in:Journal of the American Chemical Society Vol. 147; no. 11; p. 9810
Main Authors: Kloz, Miroslav, Dostál, Jakub, Mukherjee, Atripan, Pižl, Martin, Šebesta, Filip, Hill, Michael G, Gray, Harry B, Záliš, Stanislav, Vlček, Antonín
Format: Journal Article
Language:English
Published: 06.03.2025
ISSN:1520-5126, 1520-5126
Online Access:Get more information
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