Photoinduced Palladium-Catalyzed C(sp 3 )–H Phosphinoylation of Tetrahydroisoquinoline with Cl-Phosphine Oxide
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| Title: | Photoinduced Palladium-Catalyzed C(sp 3 )–H Phosphinoylation of Tetrahydroisoquinoline with Cl-Phosphine Oxide |
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| Authors: | Xue-Song Wang, Fei Ye, Zheng Xu, Jian Cao, Li-Wen Xu |
| Publication Year: | 2025 |
| Subject Terms: | Biochemistry, Medicine, Microbiology, Inorganic Chemistry, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, carbon radicals using, excited palladium complex, phosphorus radical sources, catalyzed radical c, catalyzed c, photoinduced palladium, strategy involve, phosphine oxides, phosphine oxide, key steps, easily accessible |
| Description: | A photoinduced palladium-catalyzed radical C(sp 3 )–H phosphinoylation of tetrahydroisoquinoline was reported. Easily accessible and inexpensive Cl-phosphine oxides were employed as phosphorus radical sources. The key steps in this strategy involve the generation of phosphorus and carbon radicals using the excited palladium complex. |
| Document Type: | article in journal/newspaper |
| Language: | unknown |
| DOI: | 10.1021/acs.joc.5c01483.s001 |
| Availability: | https://doi.org/10.1021/acs.joc.5c01483.s001 https://figshare.com/articles/journal_contribution/Photoinduced_Palladium-Catalyzed_C_sp_sup_3_sup_H_Phosphinoylation_of_Tetrahydroisoquinoline_with_Cl-Phosphine_Oxide/30053800 |
| Rights: | CC BY-NC 4.0 |
| Accession Number: | edsbas.DB3022F7 |
| Database: | BASE |
Nájsť tento článok vo Web of Science | Abstract: | A photoinduced palladium-catalyzed radical C(sp 3 )–H phosphinoylation of tetrahydroisoquinoline was reported. Easily accessible and inexpensive Cl-phosphine oxides were employed as phosphorus radical sources. The key steps in this strategy involve the generation of phosphorus and carbon radicals using the excited palladium complex. |
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| DOI: | 10.1021/acs.joc.5c01483.s001 |