Enabling Operando Neutron Diffraction for Solid-State Battery Studies
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| Název: | Enabling Operando Neutron Diffraction for Solid-State Battery Studies |
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| Autoři: | Ove Korjus, Sreelakshmi Anil Kumar, Ludovic Gendrin, Sébastien Vial, Claire Villevieille, Emmanuelle Suard |
| Rok vydání: | 2025 |
| Témata: | Biotechnology, Immunology, Statistics, Infectious Diseases, Space Science, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, provided valuable guidance, detailed structural characterization, 6 , 5 , 3 , 2 , state battery consisting, operando npd cell, cl solid electrolyte, solid electrolyte, cell allows, battery operation, time insight, state batteries, reaction mechanisms, providing real, positive electrode, paper presents, experiment highlighted, elevated temperatures, art solid |
| Popis: | Operando diffraction measurements are essential for advancing electrochemical energy storage by providing real-time insight into the reaction mechanisms during cycling. In solid-state batteries, these measurements also provide critical information about the solid electrolyte. This paper presents a homemade electrochemical cell explicitly designed for operando neutron powder diffraction (NPD) studies of solid-state batteries. The cell allows for detailed structural characterization of electrode materials via Rietveld refinement during battery operation, including at elevated temperatures. We demonstrate its capabilities by performing operando NPD measurements on a state-of-the-art solid-state battery consisting of a LiNi 0.5 Mn 0.3 Co 0.2 O 2 positive electrode, a Li 0.5 In counterelectrode, and a Li 6 PS 5 Cl solid electrolyte. The results of the experiment highlighted the effectiveness of this operando NPD cell and provided valuable guidance for further research in this field. |
| Druh dokumentu: | article in journal/newspaper |
| Jazyk: | unknown |
| DOI: | 10.1021/acsmaterialslett.5c00596.s001 |
| Dostupnost: | https://doi.org/10.1021/acsmaterialslett.5c00596.s001 https://figshare.com/articles/journal_contribution/Enabling_Operando_Neutron_Diffraction_for_Solid-State_Battery_Studies/29451833 |
| Rights: | CC BY-NC 4.0 |
| Přístupové číslo: | edsbas.1BEEF5E |
| Databáze: | BASE |
Nájsť tento článok vo Web of Science | Abstrakt: | Operando diffraction measurements are essential for advancing electrochemical energy storage by providing real-time insight into the reaction mechanisms during cycling. In solid-state batteries, these measurements also provide critical information about the solid electrolyte. This paper presents a homemade electrochemical cell explicitly designed for operando neutron powder diffraction (NPD) studies of solid-state batteries. The cell allows for detailed structural characterization of electrode materials via Rietveld refinement during battery operation, including at elevated temperatures. We demonstrate its capabilities by performing operando NPD measurements on a state-of-the-art solid-state battery consisting of a LiNi 0.5 Mn 0.3 Co 0.2 O 2 positive electrode, a Li 0.5 In counterelectrode, and a Li 6 PS 5 Cl solid electrolyte. The results of the experiment highlighted the effectiveness of this operando NPD cell and provided valuable guidance for further research in this field. |
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| DOI: | 10.1021/acsmaterialslett.5c00596.s001 |