Synthesis and crystal structure of [HexNH3]2[HC2O4]2·H2O: A novel hydrogen oxalate hydrate organic salt showing antimicrobial activity against Streptomyces
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| Názov: | Synthesis and crystal structure of [HexNH3]2[HC2O4]2·H2O: A novel hydrogen oxalate hydrate organic salt showing antimicrobial activity against Streptomyces |
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| Autori: | Mamadou Ba, Waly Diallo, Alhousseynou Sarr, Bocar Traore, Daouda Ndoye, Nalla Mbaye, Mamadou Sidibe, Laurent Plasseraud, Helene Cattey |
| Prispievatelia: | PLASSERAUD, Laurent |
| Zdroj: | European Journal of Chemistry. 16:251-258 |
| Informácie o vydavateľovi: | European Journal of Chemistry, 2025. |
| Rok vydania: | 2025 |
| Predmety: | [CHIM.MATE] Chemical Sciences/Material chemistry, Hydrogen oxalate, Antibacterial activity, Organic salt, [CHIM.CRIS] Chemical Sciences/Cristallography, [SDV.MP.BAC] Life Sciences [q-bio]/Microbiology and Parasitology/Bacteriology, X-ray crystal structure, Supramolecular assembly, Hydrogen bonds |
| Popis: | The new monohydrated n-hexylammonium hydrogen oxalate salt [HexNH3]2[HC2O4]2·H2O (1) (HexNH3 = C6H16N+) has been prepared at room temperature, by mixing dehydrated oxalic acid with n-hexylamine. Salt 1 isolated as single-crystals, crystallizes in the orthorhombic system (space group Pna21) with cell constants of a = 14.1534(8) Å, b = 5.6656(3) Å, c = 26.8153(16) Å, V = 2150.3(2) Å3 and Z = 4. Two n-hexylammonium cations, two hydrogen oxalate anions, and one water molecule compose the asymmetric unit. All components of salt 1 are linked through N-H···O and O-H···O hydrogen bonding interactions leading to an extended supramolecular self-assembly. Structural characterization of 1 was completed by infrared and UV-visible spectroscopy. Elemental analysis (C, H, and N) also corroborates the X-ray crystal structure. The antibacterial activity of salt 1 against a bacterial species of the genus Streptomyces, extracted from potatoes, was then investigated. The antibiotic susceptibility test revealed that the bacteria were highly sensitive to salt, from a concentration of 6 mg/mL, thus acting as an effective bactericide. |
| Druh dokumentu: | Article Other literature type |
| Popis súboru: | application/pdf |
| Jazyk: | English |
| ISSN: | 2153-2257 2153-2249 |
| DOI: | 10.5155/eurjchem.16.3.251-258.2698 |
| Prístupová URL adresa: | https://hal.science/hal-05290415v1/document https://doi.org/10.5155/eurjchem.16.3.251-258.2698 https://hal.science/hal-05290415v1 |
| Rights: | URL: http://www.eurjchem.com/index.php/eurjchem/pages/view/terms |
| Prístupové číslo: | edsair.doi.dedup.....d14ce02dde0cdebc1b9c7c3a6d4628a7 |
| Databáza: | OpenAIRE |
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Nájsť tento článok vo Web of Science | Abstrakt: | The new monohydrated n-hexylammonium hydrogen oxalate salt [HexNH3]2[HC2O4]2·H2O (1) (HexNH3 = C6H16N+) has been prepared at room temperature, by mixing dehydrated oxalic acid with n-hexylamine. Salt 1 isolated as single-crystals, crystallizes in the orthorhombic system (space group Pna21) with cell constants of a = 14.1534(8) Å, b = 5.6656(3) Å, c = 26.8153(16) Å, V = 2150.3(2) Å3 and Z = 4. Two n-hexylammonium cations, two hydrogen oxalate anions, and one water molecule compose the asymmetric unit. All components of salt 1 are linked through N-H···O and O-H···O hydrogen bonding interactions leading to an extended supramolecular self-assembly. Structural characterization of 1 was completed by infrared and UV-visible spectroscopy. Elemental analysis (C, H, and N) also corroborates the X-ray crystal structure. The antibacterial activity of salt 1 against a bacterial species of the genus Streptomyces, extracted from potatoes, was then investigated. The antibiotic susceptibility test revealed that the bacteria were highly sensitive to salt, from a concentration of 6 mg/mL, thus acting as an effective bactericide. |
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| ISSN: | 21532257 21532249 |
| DOI: | 10.5155/eurjchem.16.3.251-258.2698 |