Frank partial dislocation in Ti2AlC-MAX phase induced by matrix-Cu diffusion

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Bibliographic Details
Title: Frank partial dislocation in Ti2AlC-MAX phase induced by matrix-Cu diffusion
Authors: Yu, Wenbo, Guénolé, Julien, Ghanbaja, Jaafar, Vallet, Maxime, Guitton, Antoine
Contributors: GUITTON, Antoine, Guénolé, Julien
Source: Scripta Materialia. 191:34-39
Publisher Information: Elsevier BV, 2021.
Publication Year: 2021
Subject Terms: EELS, [SPI] Engineering Sciences [physics], diffusion, Ti2AlC, 02 engineering and technology, High-Resolution TEM, [SPI.MAT] Engineering Sciences [physics]/Materials, 01 natural sciences, 0103 physical sciences, [SPI.MECA.MSMECA] Engineering Sciences [physics]/Mechanics [physics.med-ph]/Materials and structures in mechanics [physics.class-ph], MAX phase, composite, 0210 nano-technology, Cu, atomistic simulations, [PHYS.COND] Physics [physics]/Condensed Matter [cond-mat]
Description: The control of complex nanostructures is one of the most promising strategy for designing tailored property materials. Ti2AlC, as nanolayered ternary materials combining both ceramics and metals properties, could efficiently reinforce metal matrix composite by its decomposition into nano-Ti2C particles. However, the comprehensive description of the diffusion mechanisms of Cu element into Ti2AlC during its decomposition has not yet been revealed. Herein, we report detailed characterizations of Cu and Ti2AlC interlayers by means of high-resolution electron microscopy and atomic-scale simulations. In particular, we report the formation of Ti2AlxCuyC solid solutions. Furthermore, we demonstrate the formation of Ti2C platelets and evidenced Frank partial dislocations that are not expected to be found in such material. Impacts of such defects are discussed in the framework of mechanical behavior.
Document Type: Article
Conference object
File Description: application/pdf
Language: English
ISSN: 1359-6462
DOI: 10.1016/j.scriptamat.2020.09.007
Access URL: https://hal.archives-ouvertes.fr/hal-02940841/document
https://hal.univ-lorraine.fr/hal-03102054
https://hal.archives-ouvertes.fr/hal-02940841
https://www.sciencedirect.com/science/article/pii/S1359646220305960
https://hal.archives-ouvertes.fr/hal-02940841/document
https://hal.univ-lorraine.fr/hal-03102054v1
https://hal.science/hal-02940841v1/document
https://doi.org/10.1016/j.scriptamat.2020.09.007
https://hal.science/hal-02940841v1
Rights: Elsevier TDM
Accession Number: edsair.doi.dedup.....c7ee04fabf424c4f13b647e72697bf2c
Database: OpenAIRE
Description
Abstract:The control of complex nanostructures is one of the most promising strategy for designing tailored property materials. Ti2AlC, as nanolayered ternary materials combining both ceramics and metals properties, could efficiently reinforce metal matrix composite by its decomposition into nano-Ti2C particles. However, the comprehensive description of the diffusion mechanisms of Cu element into Ti2AlC during its decomposition has not yet been revealed. Herein, we report detailed characterizations of Cu and Ti2AlC interlayers by means of high-resolution electron microscopy and atomic-scale simulations. In particular, we report the formation of Ti2AlxCuyC solid solutions. Furthermore, we demonstrate the formation of Ti2C platelets and evidenced Frank partial dislocations that are not expected to be found in such material. Impacts of such defects are discussed in the framework of mechanical behavior.
ISSN:13596462
DOI:10.1016/j.scriptamat.2020.09.007