View in EDS

Adsorption of Geosmin and 2-MIB to Porous Coordination Polymer MIL-53(Al)

Saved in:
Bibliographic Details
Title: Adsorption of Geosmin and 2-MIB to Porous Coordination Polymer MIL-53(Al)
Authors: Koji Tosa, Genki Nakamura, Kota Miyabayashi, Haruna Ishisaki, Yuta Takahashi
Source: Journal of Water and Environment Technology, Vol 20, Iss 6, Pp 212-218 (2022)
Publisher Information: Japan Society on Water Environment, 2022.
Publication Year: 2022
Subject Terms: porous coordination polymer, River, lake, and water-supply engineering (General), TC401-506, mil-53(al), 2-mib, geosmin, Environmental technology. Sanitary engineering, 01 natural sciences, metal organic framework, TD1-1066, 0105 earth and related environmental sciences
Description: Porous coordination polymers (PCPs) are porous materials with large specific surface area and pore ume, and are expected to be used as separation materials for environmental pollutants. The aim of this study was to evaluate the applicability of MIL-53(Al), a type of PCP, for the separation of geosmin and 2-MIB. The adsorption performance of MIL-53 (Al) for methylene blue and iodine was determined to be lower than that of activated carbon. The time required for the adsorption of musty odorants by MIL-53(Al) was longer than that by activated carbon, and the final adsorption amount was lower than that by activated carbon. Furthermore, adsorption isotherms for the adsorption of musty odorants by each adsorbent were prepared and their adsorption performance was evaluated. The amount of odorant adsorbed by MIL-53(Al) in pure water was extremely low compared to that of activated carbon. On the other hand, the amount of odorants adsorbed by MIL-53(Al) in raw water for water supply was not much lower than that of activated carbon. This study suggests that adsorbents with uniform pore size, such as MIL-53(Al), are less susceptible to interference by other coexisting substances. This finding may be important for future development of adsorbents for musty odorants.
Document Type: Article
Language: English
ISSN: 1348-2165
DOI: 10.2965/jwet.22-072
Access URL: https://doaj.org/article/31fbab4cd5c94bda9db97fef7dad7633
Accession Number: edsair.doi.dedup.....a3220e34b638dc38234b62bb379fb74b
Database: OpenAIRE
Description
Abstract:Porous coordination polymers (PCPs) are porous materials with large specific surface area and pore ume, and are expected to be used as separation materials for environmental pollutants. The aim of this study was to evaluate the applicability of MIL-53(Al), a type of PCP, for the separation of geosmin and 2-MIB. The adsorption performance of MIL-53 (Al) for methylene blue and iodine was determined to be lower than that of activated carbon. The time required for the adsorption of musty odorants by MIL-53(Al) was longer than that by activated carbon, and the final adsorption amount was lower than that by activated carbon. Furthermore, adsorption isotherms for the adsorption of musty odorants by each adsorbent were prepared and their adsorption performance was evaluated. The amount of odorant adsorbed by MIL-53(Al) in pure water was extremely low compared to that of activated carbon. On the other hand, the amount of odorants adsorbed by MIL-53(Al) in raw water for water supply was not much lower than that of activated carbon. This study suggests that adsorbents with uniform pore size, such as MIL-53(Al), are less susceptible to interference by other coexisting substances. This finding may be important for future development of adsorbents for musty odorants.
ISSN:13482165
DOI:10.2965/jwet.22-072