Preferentially-orientated gradient precipitates enable unique strength-ductility synergy in Mg-Sn binary alloys

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Názov: Preferentially-orientated gradient precipitates enable unique strength-ductility synergy in Mg-Sn binary alloys
Autori: Lutong Zhou, Yong Sun, Guodong Zou, Haidong Hu, Yanhui Zhang, Huhu Su, Shijian Zheng, Yulong Zhu, Peng Chen, Carlos Fernandez, Qiuming Peng
Zdroj: Journal of Materials Science & Technology. 237:298-311
Informácie o vydavateľovi: Elsevier BV, 2025.
Rok vydania: 2025
Predmety: High-resolution TEM, Density functional theory, Joule-heat treatment, Molecular dynamics
Popis: Conventional manufacturing approaches, including casting, thermal deformation and annealing, have faced great challenges in achieving both exceptional strength and ductility for Mg alloys. Herein, we report an effective strategy for simultaneously enhancing the tensile yield strength (YS = 341 ± 9.6 MPa) and elongation (EL = 15% ± 1%) of a Mg-4Sn (at.%) binary alloy at room temperature, which has been prepared by an ultrahigh-pressure treatment followed by Joule-heat treatment (UPJT). More attractively, the aging condition (80 μs, 500 Hz, 600 s) is the most time-efficient mode for aged Mg alloys. The reason is mainly associated with the presence of a unique preferentially-orientated gradient precipitate structure, as confirmed by transmission electron microscopy observations, density functional theory calculations and molecular dynamics simulations. Both experimental and theoretical results demonstrate that twin boundary-induced precipitation followed by precipitate-assisted twin boundary migration accounts for the formation of gradient precipitate structures. The fine Mg2Sn particles can effectively pin dislocation movement to enhance its strength. Comparatively, the coarse Mg2Sn particles can undergo plastic deformation and shear deformation, contributing to its high ductility. The strategy of preferentially orientated gradient structure provides a budding perspective for designing new Mg alloys with superior mechanical properties.
Druh dokumentu: Article
Jazyk: English
ISSN: 1005-0302
DOI: 10.1016/j.jmst.2025.01.082
Prístupová URL adresa: https://rgu-repository.worktribe.com/output/2801006
https://rgu-repository.worktribe.com/output/2830416
Rights: Elsevier TDM
Prístupové číslo: edsair.doi.dedup.....6fdd8de723c0459ab1755de70ad8a759
Databáza: OpenAIRE
Popis
Abstrakt:Conventional manufacturing approaches, including casting, thermal deformation and annealing, have faced great challenges in achieving both exceptional strength and ductility for Mg alloys. Herein, we report an effective strategy for simultaneously enhancing the tensile yield strength (YS = 341 ± 9.6 MPa) and elongation (EL = 15% ± 1%) of a Mg-4Sn (at.%) binary alloy at room temperature, which has been prepared by an ultrahigh-pressure treatment followed by Joule-heat treatment (UPJT). More attractively, the aging condition (80 μs, 500 Hz, 600 s) is the most time-efficient mode for aged Mg alloys. The reason is mainly associated with the presence of a unique preferentially-orientated gradient precipitate structure, as confirmed by transmission electron microscopy observations, density functional theory calculations and molecular dynamics simulations. Both experimental and theoretical results demonstrate that twin boundary-induced precipitation followed by precipitate-assisted twin boundary migration accounts for the formation of gradient precipitate structures. The fine Mg2Sn particles can effectively pin dislocation movement to enhance its strength. Comparatively, the coarse Mg2Sn particles can undergo plastic deformation and shear deformation, contributing to its high ductility. The strategy of preferentially orientated gradient structure provides a budding perspective for designing new Mg alloys with superior mechanical properties.
ISSN:10050302
DOI:10.1016/j.jmst.2025.01.082