Crystal structure and Hirshfeld surface analysis of chlorido(2,6-dimethylphenyl isocyanide)[N′-(2,6-dimethylphenyl)-N-(pyridin-2-yl)carbamimidoyl]platinum(II)
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| Title: | Crystal structure and Hirshfeld surface analysis of chlorido(2,6-dimethylphenyl isocyanide)[N′-(2,6-dimethylphenyl)-N-(pyridin-2-yl)carbamimidoyl]platinum(II) |
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| Authors: | Olga V. Repina, Elena Yu. Nevskaya, Ilya S. Kritchenkov, Victor N. Khrustalev, Alexander S. Novikov, Alexander G. Tskhovrebov, Namiq Q. Shikhaliyev, Aytan A. Niyazova, Mehmet Akkurt, Ajaya Bhattarai |
| Source: | Acta Crystallogr E Crystallogr Commun Acta Crystallographica Section E: Crystallographic Communications, Vol 81, Iss 7, Pp 587-590 (2025) |
| Publisher Information: | International Union of Crystallography (IUCr), 2025. |
| Publication Year: | 2025 |
| Subject Terms: | crystal structure, dimers, isocyanides, Crystallography, QD901-999, hirshfeld surface analysis, 2-aminopyridine, square-planar geometry, Research Communications |
| Description: | In the title compound, [Pt(C14H14N3)Cl(C9H9N)], the platinum atom has a square-planar geometry. In the crystal, dimers with R 2 2(8) motifs are formed by pairs of N—H...N hydrogen bonds. They are connected to each other through pairs of weak C—H...Cl interactions, forming a R 2 2(16) motif, creating parallel ribbons along the [011] axis. The molecular pairs are also linked by C—H...π and by π–π interactions, the shortest centroid-centroid distance [3.513 (2) Å] being observed between pyridyl rings. These weak interactions form parallel ribbons along the [010] axis. The resulting three-dimensional network ensures the cohesion of the crystal structure. Hirshfeld two-dimensional fingerprint plots revealed that the most significant interactions are H...H (58.0%), C...H/H...C (17.9%), Cl...H/H...Cl (10.7%), N...H/H...N (6.9%), C...C (2.9%), Pt...H/H...Pt (2.6%), and N...C/C...N (1.1%) contacts. |
| Document Type: | Article Other literature type |
| ISSN: | 2056-9890 |
| DOI: | 10.1107/s2056989025005079 |
| Access URL: | https://doaj.org/article/3e8c694abaa745b59bfdde769eea5777 |
| Rights: | CC BY URL: http://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| Accession Number: | edsair.doi.dedup.....65e0f6e54ecad94c5cf6f923ae4f8cc9 |
| Database: | OpenAIRE |
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Nájsť tento článok vo Web of Science | Abstract: | In the title compound, [Pt(C14H14N3)Cl(C9H9N)], the platinum atom has a square-planar geometry. In the crystal, dimers with R 2 2(8) motifs are formed by pairs of N—H...N hydrogen bonds. They are connected to each other through pairs of weak C—H...Cl interactions, forming a R 2 2(16) motif, creating parallel ribbons along the [011] axis. The molecular pairs are also linked by C—H...π and by π–π interactions, the shortest centroid-centroid distance [3.513 (2) Å] being observed between pyridyl rings. These weak interactions form parallel ribbons along the [010] axis. The resulting three-dimensional network ensures the cohesion of the crystal structure. Hirshfeld two-dimensional fingerprint plots revealed that the most significant interactions are H...H (58.0%), C...H/H...C (17.9%), Cl...H/H...Cl (10.7%), N...H/H...N (6.9%), C...C (2.9%), Pt...H/H...Pt (2.6%), and N...C/C...N (1.1%) contacts. |
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| ISSN: | 20569890 |
| DOI: | 10.1107/s2056989025005079 |