Dereplication of Bioactive Agave Saponin Fractions: The Hidden Saponins
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| Názov: | Dereplication of Bioactive Agave Saponin Fractions: The Hidden Saponins |
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| Autori: | Ana M. Simonet, Alexandra G. Durán, Francisco A. Macías |
| Prispievatelia: | Química Orgánica |
| Zdroj: | J Agric Food Chem Journal of Agricultural and Food Chemistry-2024, Vol. 72 n. 24 pp. 13740-13756 RODIN. Repositorio de Objetos de Docencia e Investigación de la Universidad de Cádiz Universidad de Cádiz |
| Informácie o vydavateľovi: | American Chemical Society (ACS), 2024. |
| Rok vydania: | 2024 |
| Predmety: | bioherbicide, steroidal saponin, coloratoside, HMAI, A. parrasana, A. parryi, A. colorata, apiose, Agave macroacantha, dereplication |
| Popis: | The good phytotoxicity and selectivity against weeds versus tomato or cress make saponin-rich fractions from Agave macroacantha, A. colorata, A. parryi, and A. parrasana attractive candidates as bioherbicides. The saponin contents have only previously been reported for A. macroacantha, and as a consequence, simultaneous dereplication has been performed on saponin-rich fractions from the other plants by mass spectrometry (MS) and nuclear magnetic resonance (NMR) spectroscopy. This strategy enables the identification of a total of 26 saponins, 14 of which have been described previously and 12 of which are proposed as new saponins. They include isomers and a new sugar chain with a β-d-apiofuranose unit. The method is corroborated by the isolation of eight dereplicated saponins from A. colorata. |
| Druh dokumentu: | Article Other literature type |
| Popis súboru: | application/pdf |
| Jazyk: | English |
| ISSN: | 1520-5118 0021-8561 |
| DOI: | 10.1021/acs.jafc.4c02308 |
| Prístupová URL adresa: | https://pubmed.ncbi.nlm.nih.gov/38838244 http://hdl.handle.net/10498/33739 |
| Rights: | CC BY URL: http://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (http://creativecommons.org/licenses/by/4.0/). |
| Prístupové číslo: | edsair.doi.dedup.....3bf4a759ac8e08628d76bb145a6521b1 |
| Databáza: | OpenAIRE |
Nájsť tento článok vo Web of Science | Abstrakt: | The good phytotoxicity and selectivity against weeds versus tomato or cress make saponin-rich fractions from Agave macroacantha, A. colorata, A. parryi, and A. parrasana attractive candidates as bioherbicides. The saponin contents have only previously been reported for A. macroacantha, and as a consequence, simultaneous dereplication has been performed on saponin-rich fractions from the other plants by mass spectrometry (MS) and nuclear magnetic resonance (NMR) spectroscopy. This strategy enables the identification of a total of 26 saponins, 14 of which have been described previously and 12 of which are proposed as new saponins. They include isomers and a new sugar chain with a β-d-apiofuranose unit. The method is corroborated by the isolation of eight dereplicated saponins from A. colorata. |
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| ISSN: | 15205118 00218561 |
| DOI: | 10.1021/acs.jafc.4c02308 |