The new heteronuclear complexes of Ti(IV) and Dy(III) in aqueous solutions
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| Názov: | The new heteronuclear complexes of Ti(IV) and Dy(III) in aqueous solutions |
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| Autori: | Ajsuvakova O., Bezryadin S., Chevela V., Ivanova V., Kuzyakin D. |
| Zdroj: | SCOPUS0970020X-2014-30-4-SID84927511778 |
| Informácie o vydavateľovi: | Oriental Scientific Publishing Company, 2014. |
| Rok vydania: | 2014 |
| Predmety: | 2. Zero hunger, 02 engineering and technology, Dysprosium(III), Titanium(IV), Aqueous solutions, 0210 nano-technology, 01 natural sciences, Oxyacid, Heteronuclear complexes, 0104 chemical sciences, 3. Good health |
| Popis: | © 2014, Oriental Scientific Publishing Company. All rights reserved. The aqueous interactions between Ti(IV), Dy(III) and citric (H4Cit), d-tartaric (d-H4Tart) and racemic tartaric acids (dl-H4Tart) acids were investigated by potentiometric titration and nuclear magnetic relaxation methods. The analysis of experimental data was performed using mathematical models to evaluate the possibility of existence of a wide species' set in the solution and to identify those of which account is sufficient to reproduce the observed pattern. The species of different nuclearity were found, the relaxation efficiency (R1) and equilibrium constants (Kpmqr) of heteronuclear complexes were calculated. It is shown that the complexation processes are strongly pH-dependent. |
| Druh dokumentu: | Article |
| ISSN: | 2231-5039 0970-020X |
| DOI: | 10.13005/ojc/300401 |
| Prístupová URL adresa: | http://www.orientjchem.org/pdf/vol30no4/OJCV030I04P1435-1440.pdf https://openrepository.ru/article?id=132231 https://openrepository.ru/article?id=176807 https://www.orientjchem.org/pdf/vol30no4/OJCV030I04P1435-1440.pdf https://www.orientjchem.org/vol30no4/the-new-heteronuclear-complexes-of-tiiv-and-dyiii-in-aqueous-solutions/ |
| Rights: | CC BY NC SA |
| Prístupové číslo: | edsair.doi.dedup.....3574e0936cd2bfdff79f51001c04d853 |
| Databáza: | OpenAIRE |
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Nájsť tento článok vo Web of Science | Abstrakt: | © 2014, Oriental Scientific Publishing Company. All rights reserved. The aqueous interactions between Ti(IV), Dy(III) and citric (H4Cit), d-tartaric (d-H4Tart) and racemic tartaric acids (dl-H4Tart) acids were investigated by potentiometric titration and nuclear magnetic relaxation methods. The analysis of experimental data was performed using mathematical models to evaluate the possibility of existence of a wide species' set in the solution and to identify those of which account is sufficient to reproduce the observed pattern. The species of different nuclearity were found, the relaxation efficiency (R1) and equilibrium constants (Kpmqr) of heteronuclear complexes were calculated. It is shown that the complexation processes are strongly pH-dependent. |
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| ISSN: | 22315039 0970020X |
| DOI: | 10.13005/ojc/300401 |