Crystal structure and Hirshfeld surface analysis of bis{(Z)-N′-[(E)-(furan-2-yl)methylidene]carbamohydrazonothioato}nickel(II) methanol disolvate
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| Název: | Crystal structure and Hirshfeld surface analysis of bis{(Z)-N′-[(E)-(furan-2-yl)methylidene]carbamohydrazonothioato}nickel(II) methanol disolvate |
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| Autoři: | Asmet N. Azizova, Gunay Z. Mammadova, Sevim Türktekin Çelikesir, Mehmet Akkurt, Ajaya Bhattarai |
| Zdroj: | Acta Crystallogr E Crystallogr Commun Acta Crystallographica Section E: Crystallographic Communications, Vol 79, Iss 7, Pp 669-673 (2023) |
| Informace o vydavateli: | International Union of Crystallography (IUCr), 2023. |
| Rok vydání: | 2023 |
| Témata: | crystal structure, Crystallography, ligands, QD901-999, hydrogen bonds, hirshfeld surface analysis, distorted square-planar geometry, 01 natural sciences, Research Communications, 0104 chemical sciences |
| Popis: | In the title complex, [Ni(C6H6N3OS)2]·2CH3OH, the NiII atom is coordinated by the S and N atoms of two N′-[(Z)-(furan-2-yl)methylidene]carbamohydrazonothioic acid ligands in a distorted square-planar geometry. The two mutual ligands bound to NiII are also connected by C—H...S interactions, while the H atoms of the NH2 group of the ligands form R 4 4(8) motifs with the O atoms of the solvent ethyl alcohol molecules. At the same time, the OH groups of the solvent ethyl alcohol molecules form parallel layers to the (011) plane by the O—H...N interactions with the ligand N atom that is not bonded to the NiII atom.. The layers are connected by van der Waals interactions. A Hirshfeld surface analysis indicates that the most important contacts are H...H (37.7%), C...H/H...C (14.6%), O...H/H...O (11.5%) and S...H/H...S (10.6%). |
| Druh dokumentu: | Article Other literature type |
| ISSN: | 2056-9890 |
| DOI: | 10.1107/s2056989023005182 |
| Přístupová URL adresa: | https://pubmed.ncbi.nlm.nih.gov/37601570 https://doaj.org/article/619568616e6248409d2b247af7589eec https://avesis.erciyes.edu.tr/publication/details/6f6b3627-ae10-4227-99a9-b93f78bfef08/oai |
| Rights: | CC BY URL: http://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| Přístupové číslo: | edsair.doi.dedup.....25bb0a0f5e76f61b2cc66a15fb60e28b |
| Databáze: | OpenAIRE |
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Nájsť tento článok vo Web of Science | Abstrakt: | In the title complex, [Ni(C6H6N3OS)2]·2CH3OH, the NiII atom is coordinated by the S and N atoms of two N′-[(Z)-(furan-2-yl)methylidene]carbamohydrazonothioic acid ligands in a distorted square-planar geometry. The two mutual ligands bound to NiII are also connected by C—H...S interactions, while the H atoms of the NH2 group of the ligands form R 4 4(8) motifs with the O atoms of the solvent ethyl alcohol molecules. At the same time, the OH groups of the solvent ethyl alcohol molecules form parallel layers to the (011) plane by the O—H...N interactions with the ligand N atom that is not bonded to the NiII atom.. The layers are connected by van der Waals interactions. A Hirshfeld surface analysis indicates that the most important contacts are H...H (37.7%), C...H/H...C (14.6%), O...H/H...O (11.5%) and S...H/H...S (10.6%). |
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| ISSN: | 20569890 |
| DOI: | 10.1107/s2056989023005182 |