Review on Catalytic Meinwald Rearrangement of Epoxides.

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Názov: Review on Catalytic Meinwald Rearrangement of Epoxides.
Autori: Zhang, Yulong, Hu, Bowen, Chen, Yushuang, Wang, Zhen
Zdroj: Chemistry - A European Journal; 10/23/2024, Vol. 30 Issue 59, p1-16, 16p
Predmety: VALUE engineering, CARBONYL compounds, EPOXY compounds, RESEARCH personnel, CATALYSTS
Abstrakt: The past few decades have witnessed tremendous development within epoxides. Among the many known reactions involving epoxide, Meinwald rearrangements represent one of the most important and attractive approaches, which can transform epoxides into versatile carbonyl compounds. Given the high efficiency of this protocol, substantial efforts have been made by researchers by utilizing multiple catalyst systems. This review provides an overview of recent advances in the Meinwald rearrangement (from 2014 onward), along with detailed discussions on mechanistic insights. This review aims to highlight the importance and value of these methodologies, thereby promoting further investigation and application. [ABSTRACT FROM AUTHOR]
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Databáza: Complementary Index
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Abstrakt:The past few decades have witnessed tremendous development within epoxides. Among the many known reactions involving epoxide, Meinwald rearrangements represent one of the most important and attractive approaches, which can transform epoxides into versatile carbonyl compounds. Given the high efficiency of this protocol, substantial efforts have been made by researchers by utilizing multiple catalyst systems. This review provides an overview of recent advances in the Meinwald rearrangement (from 2014 onward), along with detailed discussions on mechanistic insights. This review aims to highlight the importance and value of these methodologies, thereby promoting further investigation and application. [ABSTRACT FROM AUTHOR]
ISSN:09476539
DOI:10.1002/chem.202402469