In EDS ansehen

Flow electrochemical oxidation of N-nitrosamines to N-nitramines.

Gespeichert in:
Bibliographische Detailangaben
Titel: Flow electrochemical oxidation of N-nitrosamines to N-nitramines.
Autoren: Ali, Rojan1 (AUTHOR), Matsui, Kai1 (AUTHOR), Šadauskis, Jānis1 (AUTHOR), Catherall, Amanda2 (AUTHOR), Wirth, Thomas1 (AUTHOR) wirth@cf.ac.uk
Quelle: Chemical Communications. 9/16/2025, Vol. 61 Issue 72, p13671-13674. 4p.
Schlagwörter: *NITROAMINES, *ELECTROLYTIC oxidation, *CHEMICAL processes, *NITRO compounds, *ELECTROLYSIS, *OXYGEN, *BIOSYNTHESIS, *NITROSOAMINES
Abstract: N-Nitro groups are a key functionality found in most energetic compounds. Conventional synthetic routes require the use of harsh reagents, such as fuming nitric acid. As an alternative, a biphasic electrochemical flow synthesis of N-nitramines from the oxidation of N-nitrosamines using molecular oxygen has been developed, proceeding via paired electrolysis. [ABSTRACT FROM AUTHOR]
Datenbank: Academic Search Index
Beschreibung
Abstract:N-Nitro groups are a key functionality found in most energetic compounds. Conventional synthetic routes require the use of harsh reagents, such as fuming nitric acid. As an alternative, a biphasic electrochemical flow synthesis of N-nitramines from the oxidation of N-nitrosamines using molecular oxygen has been developed, proceeding via paired electrolysis. [ABSTRACT FROM AUTHOR]
ISSN:13597345
DOI:10.1039/d5cc03458b