Oxygen out, sulfur in: The alkali metal sulfidotungstates K2[WS4] and novel Na2[WS4] ⋅ 4 H2O

An attempt to synthesize a holmium sulfidotungstate using potassium polysulfides as reactive flux resulted in orange single crystals of K2[WS4], isotypic to K2[MoS4] (orthorhombic; Pnma; a=935.10(3), b=694.22(2), c=1221.85(4) pm; Z=4). A similar attempt to obtain a neodymium sulfidotungstate with so...

Full description

Bibliographic Details

Published in:	Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 648; no. 23
Main Authors:	Knies, Benjamin, Hartenbach, Ingo
Format:	Journal Article
Language:	English
Published:	13.12.2022
Subjects:	alkali metal crystal structure spectroscopy sulfidotungstates thiotungstates
ISSN:	0044-2313, 1521-3749
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!