Structure and electrochromism of two-dimensional octahedral molecular sieve h'-WO 3

Octahedral molecular sieves (OMS) are built of transition metal-oxygen octahedra that delimit sub-nanoscale cavities. Compared to other microporous solids, OMS exhibit larger versatility in properties, provided by various redox states and magnetic behaviors of transition metals. Hence, OMS offer opp...

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Veröffentlicht in:Nature communications Jg. 10; H. 1; S. 327
Hauptverfasser: Besnardiere, Julie, Ma, Binghua, Torres-Pardo, Almudena, Wallez, Gilles, Kabbour, Houria, González-Calbet, José M, Von Bardeleben, Hans Jürgen, Fleury, Benoit, Buissette, Valérie, Sanchez, Clément, Le Mercier, Thierry, Cassaignon, Sophie, Portehault, David
Format: Journal Article
Sprache:Englisch
Veröffentlicht: England 01.12.2019
ISSN:2041-1723
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Abstract Octahedral molecular sieves (OMS) are built of transition metal-oxygen octahedra that delimit sub-nanoscale cavities. Compared to other microporous solids, OMS exhibit larger versatility in properties, provided by various redox states and magnetic behaviors of transition metals. Hence, OMS offer opportunities in electrochemical energy harnessing devices, including batteries, electrochemical capacitors and electrochromic systems, provided two conditions are met: fast exchange of ions in the micropores and stability upon exchange. Here we unveil a novel OMS hexagonal polymorph of tungsten oxide called h'-WO , built of (WO ) tunnel cavities. h'-WO is prepared by a one-step soft chemistry aqueous route leading to the hydrogen bronze h'-H WO . Gentle heating results in h'-WO with framework retention. The material exhibits an unusual combination of 1-dimensional crystal structure and 2-dimensional nanostructure that enhances and fastens proton (de)insertion for stable electrochromic devices. This discovery paves the way to a new family of mixed valence functional materials with tunable behaviors.
AbstractList Octahedral molecular sieves (OMS) are built of transition metal-oxygen octahedra that delimit sub-nanoscale cavities. Compared to other microporous solids, OMS exhibit larger versatility in properties, provided by various redox states and magnetic behaviors of transition metals. Hence, OMS offer opportunities in electrochemical energy harnessing devices, including batteries, electrochemical capacitors and electrochromic systems, provided two conditions are met: fast exchange of ions in the micropores and stability upon exchange. Here we unveil a novel OMS hexagonal polymorph of tungsten oxide called h'-WO , built of (WO ) tunnel cavities. h'-WO is prepared by a one-step soft chemistry aqueous route leading to the hydrogen bronze h'-H WO . Gentle heating results in h'-WO with framework retention. The material exhibits an unusual combination of 1-dimensional crystal structure and 2-dimensional nanostructure that enhances and fastens proton (de)insertion for stable electrochromic devices. This discovery paves the way to a new family of mixed valence functional materials with tunable behaviors.
Author Ma, Binghua
Besnardiere, Julie
Le Mercier, Thierry
Torres-Pardo, Almudena
Wallez, Gilles
González-Calbet, José M
Cassaignon, Sophie
Buissette, Valérie
Fleury, Benoit
Von Bardeleben, Hans Jürgen
Sanchez, Clément
Kabbour, Houria
Portehault, David
Author_xml – sequence: 1
  givenname: Julie
  surname: Besnardiere
  fullname: Besnardiere, Julie
  organization: Sorbonne Université, CNRS, Collège de France, PSL Research University, Laboratoire Chimie de la Matière Condensée de Paris, LCMCP, 4 Place Jussieu, F-75005, Paris, France
– sequence: 2
  givenname: Binghua
  orcidid: 0000-0002-8440-3274
  surname: Ma
  fullname: Ma, Binghua
  organization: Sorbonne Université, CNRS, Collège de France, PSL Research University, Laboratoire Chimie de la Matière Condensée de Paris, LCMCP, 4 Place Jussieu, F-75005, Paris, France
– sequence: 3
  givenname: Almudena
  orcidid: 0000-0002-1667-4072
  surname: Torres-Pardo
  fullname: Torres-Pardo, Almudena
  organization: Departamento de Química Inorgánica, Facultad de Químicas, Universidad Complutense, 28040, Madrid, Spain
– sequence: 4
  givenname: Gilles
  orcidid: 0000-0002-2113-1144
  surname: Wallez
  fullname: Wallez, Gilles
  organization: PSL Research University, Chimie ParisTech, CNRS, Institut de Recherche de Chimie de Paris, 11 rue Pierre et Marie Curie, 75005, Paris, France
– sequence: 5
  givenname: Houria
  orcidid: 0000-0002-9081-3261
  surname: Kabbour
  fullname: Kabbour, Houria
  organization: Univ. Lille, CNRS, ENSCL, Centrale Lille, Univ. Artois, UMR 8181-UCCS-Unité de Catalyse et de Chimie du Solide, F-59000, Lille, France
– sequence: 6
  givenname: José M
  orcidid: 0000-0001-8957-2651
  surname: González-Calbet
  fullname: González-Calbet, José M
  organization: Centro Nacional de Microscopía Electrónica, Universidad Complutense, 28040, Madrid, Spain
– sequence: 7
  givenname: Hans Jürgen
  surname: Von Bardeleben
  fullname: Von Bardeleben, Hans Jürgen
  organization: Sorbonne Université, CNRS, Institut des Nanosciences de Paris, INSP, 4 Place Jussieu, F-75005, Paris, France
– sequence: 8
  givenname: Benoit
  orcidid: 0000-0003-4723-5037
  surname: Fleury
  fullname: Fleury, Benoit
  organization: Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, IPCM, F-75005, Paris, France
– sequence: 9
  givenname: Valérie
  orcidid: 0000-0001-5119-9580
  surname: Buissette
  fullname: Buissette, Valérie
  organization: Solvay, Centre de Recherches d'Aubervilliers, 52 rue de la Haie-Coq, 93308, Aubervilliers Cedex, France
– sequence: 10
  givenname: Clément
  orcidid: 0000-0002-6426-4844
  surname: Sanchez
  fullname: Sanchez, Clément
  organization: Sorbonne Université, CNRS, Collège de France, PSL Research University, Laboratoire Chimie de la Matière Condensée de Paris, LCMCP, 4 Place Jussieu, F-75005, Paris, France
– sequence: 11
  givenname: Thierry
  orcidid: 0000-0003-0653-8234
  surname: Le Mercier
  fullname: Le Mercier, Thierry
  organization: Solvay, Centre de Recherches d'Aubervilliers, 52 rue de la Haie-Coq, 93308, Aubervilliers Cedex, France
– sequence: 12
  givenname: Sophie
  orcidid: 0000-0001-6599-3718
  surname: Cassaignon
  fullname: Cassaignon, Sophie
  organization: Sorbonne Université, CNRS, Collège de France, PSL Research University, Laboratoire Chimie de la Matière Condensée de Paris, LCMCP, 4 Place Jussieu, F-75005, Paris, France
– sequence: 13
  givenname: David
  orcidid: 0000-0003-4914-4913
  surname: Portehault
  fullname: Portehault, David
  email: david.portehault@sorbonne-universite.fr
  organization: Sorbonne Université, CNRS, Collège de France, PSL Research University, Laboratoire Chimie de la Matière Condensée de Paris, LCMCP, 4 Place Jussieu, F-75005, Paris, France. david.portehault@sorbonne-universite.fr
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Snippet Octahedral molecular sieves (OMS) are built of transition metal-oxygen octahedra that delimit sub-nanoscale cavities. Compared to other microporous solids, OMS...
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Title Structure and electrochromism of two-dimensional octahedral molecular sieve h'-WO 3
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