Deciphering the Role of Anions and Secondary Coordination Sphere in Tuning Anisotropy in Dy(III) Air‐Stable D5h SIMs

Precise control of the crystal field and symmetry around the paramagnetic spin centre has recently facilitated the engineering of high‐temperature single‐ion magnets (SIMs), the smallest possible units for future spin‐based devices. In the present work, we report a series of air‐stable seven coordin...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 28; no. 4; pp. e202103585 - n/a
Main Authors:	Gupta, Sandeep K., Dey, Sourav, Rajeshkumar, Thayalan, Rajaraman, Gopalan, Murugavel, Ramaswamy
Format:	Journal Article
Language:	English
Published:	Weinheim Wiley Subscription Services, Inc 19.01.2022
Subjects:	Anions Anisotropy axiality blocking temperature Bonding strength Chemistry Coordination D5h dysprosium(III) Iodides Magnetic induction Magnetic relaxation Magnets Quantum tunnelling single-ion magnet Symmetry
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
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