Rotaxane CoII Complexes as Field‐Induced Single‐Ion Magnets

Mechanically chelating ligands have untapped potential for the engineering of metal ion properties. Here we demonstrate this principle in the context of CoII‐based single‐ion magnets. Using multi‐frequency EPR, susceptibility and magnetization measurements we found that these complexes show some of...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 60; no. 29; pp. 16051 - 16058
Main Authors:	Cirulli, Martina, Salvadori, Enrico, Zhang, Zhi‐Hui, Dommett, Michael, Tuna, Floriana, Bamberger, Heiko, Lewis, James E. M., Kaur, Amanpreet, Tizzard, Graham J., Slageren, Joris, Crespo‐Otero, Rachel, Goldup, Stephen M., Roessler, Maxie M.
Format:	Journal Article
Language:	English
Published:	WEINHEIM Wiley 12.07.2021 Wiley Subscription Services, Inc John Wiley and Sons Inc
Edition:	International ed. in English
Subjects:	Chelation Chemistry Chemistry, Multidisciplinary Coordination compounds electron paramagnetic resonance Ligands Magnetic properties magnetism Magnets Metal complexes Metal ions Physical Sciences Rotaxanes Science & Technology single ion magnets zero-field splitting SPIN-CROSSOVER METAL TEMPLATE SYNTHESIS single ion magnets MAGNETIZATION MOLECULE MAGNETS MECHANICAL BOND magnetism RELAXATION PARAMETERS ANISOTROPY CONFORMATIONS zero-field splitting LIGANDS DIALING-UP electron paramagnetic resonance rotaxanes
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
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